Eric Rivard
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Explore the profile of Eric Rivard including associated specialties, affiliations and a list of published articles.
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111
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Recent Articles
1.
Medroa Del Pino W, Forero Pico A, Muralidharan A, Gupta M, Rivard E
Dalton Trans
. 2025 Jan;
54(7):3057-3064.
PMID: 39817837
This article provides an alternative pathway towards cyclosilapentenes (, SiH2-iPr and SpiroSi) involving the use of Rieke magnesium to activate the requisite dienes for synthesis. Subsequent metal-mediated dehydrocoupling of cyclosilapentene...
2.
Frenette B, Ferguson M, Rivard E
Chemistry
. 2024 Aug;
30(68):e202402899.
PMID: 39212600
Several complexes of the intramolecular frustrated Lewis pair (FLP)-supported P(-1) ligand [PrP(CH)BCy{P}] are presented (Cy=cyclohexyl). Chief among these is the first example of a monomeric zinc bis(phosphido) complex, which was...
3.
Muralidharan A, Frenette B, Wicke J, Omana A, Ferguson M, Rivard E
Dalton Trans
. 2024 Apr;
53(16):7206-7212.
PMID: 38584458
The frustrated Lewis pair (FLP) adducts PB{ECl} (PB = PrP(CH)BCy; Cy = cyclohexyl; E = Si, Ge) were used to access a bis(alkynyl)-functionalized silylene and a germylene; the goal behind...
4.
Ackermann M, Szlosek R, Riesinger C, Seidl M, Timoshkin A, Rivard E, et al.
Chemistry
. 2023 Nov;
30(12):e202303680.
PMID: 38009601
The syntheses of novel N-heterocyclic carbene (NHC) adducts of group 13, 14 and 15 element hydrides are reported. Salt metathesis reactions between NaPH and IDipp ⋅ GeH BH OTf (1)...
5.
Frenette B, Rivard E
Chemistry
. 2023 Sep;
29(65):e202302332.
PMID: 37677126
Frustrated Lewis pairs (FLPs) have been the subject of considerable study since the field's inception. While much of the research into FLPs has centered around small molecule activation for diverse...
6.
Medroa Del Pino W, Ferero Pico A, Gupta M, Rivard E
Chem Commun (Camb)
. 2023 May;
59(45):6849-6852.
PMID: 37195801
A series of air-stable poly(cyclogermapentene)s were prepared the dehydrocoupling of 1,1-dihydrocyclogermapentene monomers. Exposure of the resulting polygermanes to UV light led to elimination of organobutadiene from the polymer side chains...
7.
Ackermann M, Seidl M, Grande R, Zhou Y, Ferguson M, Timoshkin A, et al.
Chem Sci
. 2023 Mar;
14(9):2313-2317.
PMID: 36873855
The formation of novel cationic mixed main group compounds is reported revealing a chain composed of different elements of group 13, 14, and 15. Reactions of different pnictogenylboranes REBH·NMe (E...
8.
Baird S, Hupf E, Watson I, Ferguson M, Rivard E
Chem Commun (Camb)
. 2023 Feb;
59(20):2903-2906.
PMID: 36752173
An organometallic tetrahedron-shaped indium(I) tetramer [(IPrCH)In] (IPrCH = [(MeCNDipp)CCH]; Dipp = 2,6-PrCH) supported by anionic N-heterocyclic olefin (aNHO) ligands is reported. The monomeric unit of this species exhibits both Lewis...
9.
Bykowski J, Sinclair J, Trach J, Ferguson M, Rivard E
Dalton Trans
. 2023 Jan;
52(6):1602-1607.
PMID: 36645418
We report mild routes for the deposition of crystalline films of elemental tin the formation and subsequent decomposition of unstable tin(II) hydrides. Specifically, we take advantage of efficient OBu/H metathesis...
10.
Frenette B, Trach J, Ferguson M, Rivard E
Angew Chem Int Ed Engl
. 2023 Jan;
62(10):e202218587.
PMID: 36625676
We report phosphinidenes (PR) stabilized by an intramolecular frustrated Lewis pair (FLP) chelate. These adducts include the parent phosphinidene, PH, which is accessed via thermolysis of coordinated HPCO. The reported...