Fast Nucleation and Growth of ZIF-8 Nanocrystals Monitored by Time-resolved in Situ Small-angle and Wide-angle X-ray Scattering

Overview

Journal Angew Chem Int Ed Engl

Specialty Chemistry

Date 2011 Jul 13

PMID 21748830

Citations 33

Authors

Janosch Cravillon

Christian A Schroder

Roman Nayuk

Jeremie Gummel

Klaus Huber

Michael Wiebcke

Affiliations

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Abstract

Prenucleation clusters: in situ synchrotron X-ray scattering with a one-second time resolution revealed the occurrence of nano-sized clusters during the nucleation and early growth of nanocrystals of a zeolitic imidazolate framework (ZIF). The complex crystallization process exhibits similarities with crystallization processes of zeolites from solution. Hmim= 2-methylimidazole.

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