1-Methyl-1-azonia-3,5-diaza-7-phosphatricyclo-[3.3.1.1]decane Tetra-fluoro-borate
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Abstract
The title compound, C(7)H(15)N(3)P(+)·BF(4) (-) or [PTA-Me][BF(4)], is the N-methyl-ated derivative of the well known water-soluble amino-phosphine 1,3,5-triaza-7-phosphaadamantane (PTA). The asymmetric unit consists of a cage-like cation [PTA-Me](+) and a disordered tetra-fluoro-borate anion; two F atoms are disordered equally over two sites. A network of weak inter-molecular C-H⋯F hydrogen bonds results in a three-dimensional supra-molecular assembly.
Citing Articles
Sgarbossa P, Sliwinska-Hill U, Guedes da Ilva M, Bazanow B, Pawlak A, Jackulak N Materials (Basel). 2019; 12(23).
PMID: 31779206 PMC: 6926962. DOI: 10.3390/ma12233907.
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