Simultaneous Self-assembly of a Cage-like Silver(I) Complex Encapsulating an Ag6 Neutral Cluster Core and Carbon Dioxide Fixation

Overview

Journal Chem Commun (Camb)

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2010 Dec 18

PMID 21165465

Citations 7

Authors

Di Sun

Geng-Geng Luo

Na Zhang

Rong-Bin Huang

Lan-Sun Zheng

Affiliations

Soon will be listed here.

Abstract

A novel mixed-valent Ag(I)/Ag(0) T(h)-Ag(34) cage was obtained by a one-pot ultrasonic reaction. In the shell of the cage, CO(3)(2-) anion is derived from atmospheric CO(2) and adopts a rare μ(6) bridging mode to link the Ag(I) ions. In the core of the cage, an unprecedented neutral metal cluster with six zero-valent silver atoms is encapsulated.

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