» Articles » PMID: 20820545

Thermosensitive Gating Effect and Selective Gas Adsorption in a Porous Coordination Nanocage

Overview
Specialty Chemistry
Date 2010 Sep 8
PMID 20820545
Citations 10
Authors
Affiliations
Soon will be listed here.
Abstract

A porous coordination nanocage functionalized with 24 triisopropylsilyl groups exhibits a remarkable thermosensitive gate opening phenomenon and demonstrates a molecular sieving effect at a certain temperature range, which can be used for gas separation purposes.

Citing Articles

Lattice-driven gating in a Cu-based zeolitic imidazolate framework for efficient high-temperature hydrogen isotope separation.

Jung M, Park J, Muhammad R, Park T, Jung S, Yi J Nat Commun. 2025; 16(1):2032.

PMID: 40016192 PMC: 11868644. DOI: 10.1038/s41467-025-56649-5.


Temperature-Dependent Separation of CO from Light Hydrocarbons in a Porous Self-Assembly of Vertexes Sharing Octahedra.

Li S, Li Q, Chen T, Ji Z, Li G, Wu M Adv Sci (Weinh). 2024; 11(14):e2308028.

PMID: 38308108 PMC: 11005747. DOI: 10.1002/advs.202308028.


Exploring porphyrins induced carbon nanocone TM-PICNC (TM = Sc, Ti, V, Cr, Fe Co, Ni, Cu, and Zn) as a highly sensitive sensor for CO gas detection in presence O and HO molecules: a computational study.

Wu G, Arshadi S, Pouralimardan O, Abbasi V, Vessally E Front Chem. 2023; 11:1305362.

PMID: 38093818 PMC: 10716792. DOI: 10.3389/fchem.2023.1305362.


Porous Metal-Organic Cages Based on Rigid Bicyclo[2.2.2]oct-7-ene Type Ligands: Synthesis, Structure, and Gas Uptake Properties.

Donagueda Suso B, Legrand A, Weetman C, Kennedy A, Fletcher A, Furukawa S Chemistry. 2023; 29(32):e202300732.

PMID: 37022280 PMC: 10947411. DOI: 10.1002/chem.202300732.


Metal-Organic Polyhedra as Building Blocks for Porous Extended Networks.

Khobotov-Bakishev A, Hernandez-Lopez L, von Baeckmann C, Albalad J, Carne-Sanchez A, Maspoch D Adv Sci (Weinh). 2022; 9(11):e2104753.

PMID: 35119223 PMC: 9008419. DOI: 10.1002/advs.202104753.