Mathematical Models of the Homochiralisation of Crystals by Grinding
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Molecular Biology
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We review the existing mathematical models which describe physicochemical mechanisms capable of producing a symmetry-breaking transition to a state in which one chirality dominates the other. A new model is proposed, with the aim of elucidating the fundamental processes at work in the crystal grinding systems of Viedma (Phys Rev Lett 94:065504, 2005) and Noorduin (J Am Chem Soc 130:1158-1159, 2008). We simplify the model as far as possible to uncover the fundamental competitive process which causes the symmetry-breaking, and analyse other simplifications which might be expected to show symmetry-breaking.
Spontaneous Emergence of Transient Chirality in Closed, Reversible Frank-like Deterministic Models.
Buhse T, Micheau J Orig Life Evol Biosph. 2022; 52(1-3):3-20.
PMID: 35680768 DOI: 10.1007/s11084-022-09621-y.