» Articles » PMID: 19438203

Rhodium-catalyzed C-C Bond Formation Via Heteroatom-directed C-H Bond Activation

Overview
Journal Chem Rev
Specialty Chemistry
Date 2009 May 15
PMID 19438203
Citations 306
Authors
Affiliations
Soon will be listed here.
Citing Articles

Oxidative coupling of N-nitrosoanilines with substituted allyl alcohols under rhodium (III) catalysis.

Chaudhary P Front Chem. 2025; 12:1506493.

PMID: 39742134 PMC: 11685039. DOI: 10.3389/fchem.2024.1506493.


Mechanistic Studies and Identification of Catalyst Deactivation Pathways for Pyridine(diimine) Iron Catalyzed C(sp)-H Borylation.

Zhang T, Pabst T, Hoyt J, Pecoraro M, Chirik P ACS Catal. 2024; 14(18):13999-14011.

PMID: 39555381 PMC: 11563351. DOI: 10.1021/acscatal.4c03744.


Reductive Amination of Carbonyl C-C Bonds Enables Formal Nitrogen Insertion.

Amber C, Gottemann L, Steele R, Petitjean T, Sarpong R J Org Chem. 2024; 89(23):17655-17663.

PMID: 39509344 PMC: 11624976. DOI: 10.1021/acs.joc.4c02400.


Rh(iii)-catalyzed building up of used heterocyclic cations: facile access to white-light-emitting materials.

Zhang J, Sun T, Wang K, Hu R, Zhou C, Ge H Chem Sci. 2024; 15(31):12270-12276.

PMID: 39118641 PMC: 11304525. DOI: 10.1039/d4sc02188f.


Repurposing a supramolecular iridium catalyst secondary Zn⋯O[double bond, length as m-dash]C weak interactions between the ligand and substrate leads to -selective C(sp)-H borylation of benzamides with unusual kinetics.

Trouve J, Delahaye V, Tomasini M, Rajeshwaran P, Roisnel T, Poater A Chem Sci. 2024; 15(30):11794-11806.

PMID: 39092112 PMC: 11290415. DOI: 10.1039/d4sc01515k.


References
1.
Parthasarathy K, Jeganmohan M, Cheng C . Rhodium-catalyzed one-pot synthesis of substituted pyridine derivatives from alpha,beta-unsaturated ketoximes and alkynes. Org Lett. 2007; 10(2):325-8. DOI: 10.1021/ol7028367. View

2.
Ueura K, Satoh T, Miura M . Rhodium-catalyzed arylation using arylboron compounds: efficient coupling with aryl halides and unexpected multiple arylation of benzonitrile. Org Lett. 2005; 7(11):2229-31. DOI: 10.1021/ol050590b. View

3.
Thalji R, Ahrendt K, Bergman R, Ellman J . Annulation of aromatic imines via directed C-H bond activation. J Org Chem. 2005; 70(17):6775-81. DOI: 10.1021/jo050757e. View

4.
Billingsley K, Buchwald S . A general and efficient method for the Suzuki-Miyaura coupling of 2-pyridyl nucleophiles. Angew Chem Int Ed Engl. 2008; 47(25):4695-8. PMC: 2748766. DOI: 10.1002/anie.200801465. View

5.
Chang D, Lee D, Hong B, Choi J, Jun C . A new solvent system for recycling catalysts for chelation-assisted hydroacylation of olefins with primary alcohols. J Am Chem Soc. 2004; 126(2):424-5. DOI: 10.1021/ja038071w. View