Total Synthesis of (+/-)-terpestacin and (+/-)-11-epi-terpestacin

Overview

Journal J Org Chem

Publisher American Chemical Society

Specialty Chemistry

Date 2007 Jul 17

PMID 17630803

Citations 8

Authors

Gideon O Berger

Marcus A Tius

Affiliations

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Abstract

The total synthesis of racemic terpestacin and 11-epi-terpestacin using the allene ether Nazarov reaction as the key step is described. All stereochemistry is derived from the stereogenic carbon atom that is formed during the Nazarov reaction.

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