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Highly Selective Optical Fluoride Ion Sensor with Submicromolar Detection Limit Based on Aluminum(III) Octaethylporphyrin in Thin Polymeric Film

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Journal J Am Chem Soc
Specialty Chemistry
Date 2005 Apr 14
PMID 15826159
Citations 13
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Abstract

A highly selective, sensitive, and reversible fluoride optical sensing film based on aluminum(III)octaethylporphyrin as a fluoride ionophore and a lipophilic pH indicator as the optical transducer is described. The fluoride optical sensing films exhibit a submicromolar detection limit and high discrimination for fluoride over several lipophilic anions such as nitrate, perchlorate, and thiocyanate.

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