Oxidation-resistant, Sterically Demanding Phenanthrolines As Supporting Ligands for Copper(I) Nitrene Transfer Catalysts

Overview

Journal Chem Commun (Camb)

Publisher Royal Society of Chemistry

Specialty Chemistry

Date 2004 Jul 21

PMID 15263951

Citations 7

Authors

Charles W Hamilton

David S Laitar

Joseph P Sadighi

Affiliations

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Abstract

New 1,10-phenanthroline ligands have been synthesized with C6F5- or 2,4,6-(CF3)3C6H2- groups in the 2- and 9-positions; a cationic copper(I) complex of the latter catalyses nitrene transfer to the C-H bonds of electron-rich arenes.

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