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Mild and Efficient Aryl-alkenyl Coupling Via Pd(II) Catalysis in the Presence of Oxygen or Cu(II) Oxidants

Overview
Journal J Org Chem
Specialty Chemistry
Date 2002 Oct 2
PMID 12354008
Citations 19
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Abstract

We report herein a mild and efficient method for carbon-carbon bond formation between aryl stannanes and olefins via Pd(II) catalysis in the presence of oxygen or Cu(II) oxidants as a reoxidant. The process allows reactions between various olefins and aryl stannanes of varying electron density. Coupling methods under these oxidation conditions are comparatively described, and the benefits and limitations are also discussed.

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