A New Tin-free Source of Amidyl Radicals

Overview

Journal Org Lett

Publisher American Chemical Society

Specialties Biochemistry
Chemistry

Date 2002 Aug 3

PMID 12153215

Citations 13

Authors

Fabien Gagosz

Cecile Moutrille

Samir Z Zard

Affiliations

Soon will be listed here.

Abstract

[reaction: see text] The readily available N-(O-ethyl thiocarbonylsulfanyl)amides are powerful amidyl radical precursors that undergo 5-exo cyclization to give pyrrolidinone derivatives via a radical-chain reaction initiated by a small amount of lauroyl peroxide.

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