Polyoxometalates As Reduction Catalysts: Deoxygenation and Hydrogenation of Carbonyl Compounds

Overview

Journal Angew Chem Int Ed Engl

Specialty Chemistry

Date 1999 Dec 22

PMID 10602187

Citations 5

Authors

Kogan V

Aizenshtat

Neumann

Affiliations

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Abstract

Excellent deoxygenation of ketones and aldehydes is achieved with Keggin-type polyoxometalates in the presence of hydrogen (see Equation (1) for an example). The mixed addenda phosphovanadomolybdate [PV(2)Mo(10)O(4)](5-) was found to be the best catalyst. X-ray diffraction and IR studies suggest that the polyoxometalates are structurally stable under the strongly reducing conditions.

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