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Wayne W Lukens

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Articles 51
Citations 250
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Recent Articles
1.
Aguirre Quintana L, Lussier D, Wacker J, Bajaj A, Russo D, Cosby A, et al.
J Am Chem Soc . 2024 Nov; 146(46):31671-31680. PMID: 39500515
We report the synthesis and characterization of the macrocyclic californium derivative Na[Cf(HO)(DOTA)] (DOTA = 1,4,7,10-tetraazacyclododecane-1,4,7,10-tetraacetate), , which was studied in comparison to its dysprosium counterpart, Na[Dy(HO)(DOTA)], . Divergent spectroscopic and...
2.
Peterson A, Adewuyi J, Woods J, Wacker J, Lukens W, Abergel R, et al.
Inorg Chem . 2024 Oct; 63(42):19752-19758. PMID: 39375943
Curium's stable redox chemistry and ability to emit strong metal-based luminescence make it uniquely suitable for spectroscopic studies among the actinide series. Targeted ligand and coordination compound design can support...
3.
Peterson A, Kelly S, Arino T, Gunther S, Ouellette E, Wacker J, et al.
Inorg Chem . 2024 Sep; 63(39):18417-18428. PMID: 39284039
Amidate-based ligands (-(-butyl)isobutyramide, ) bind κ to form homoleptic, 8-coordinate complexes with tetravalent Np (Np(ITA), ) and Pu (Pu(ITA), ). These compounds complete an isostructural series from Th, U-Pu and...
4.
Wacker J, Woods J, Rupert P, Peterson A, Allaire M, Lukens W, et al.
Nat Commun . 2024 Jul; 15(1):5741. PMID: 39009580
Targeted alpha therapy (TAT) pairs the specificity of antigen targeting with the lethality of alpha particles to eradicate cancerous cells. Actinium-225 [Ac; t = 9.920(3) days] is an alpha-emitting radioisotope...
5.
Wedal J, Moore W, Lukens W, Evans W
Inorg Chem . 2024 Jan; 63(6):2945-2953. PMID: 38279200
Metal complexes with unpaired electrons in orbitals of different angular momentum quantum numbers (., f and d orbitals) are unusual and opportunities to study the interactions among these electrons are...
6.
Nguyen T, Paul E, Lukens W, Hayton T
Inorg Chem . 2023 Apr; 62(16):6447-6457. PMID: 37053543
The reaction of 1 equiv of 1-azidoadamantane with [U(NR)] (R = SiMe) in EtO results in the formation of [U(NR)(NAd)] (, Ad = 1-adamantyl) in good yields. The electronic structure...
7.
Moreau L, Lapsheva E, Amaro-Estrada J, Gau M, Carroll P, Manor B, et al.
Chem Sci . 2022 Mar; 13(6):1759-1773. PMID: 35282640
This study presents the role of 5d orbitals in the bonding, and electronic and magnetic structure of Ce imido and oxo complexes synthesized with a tris(hydroxylaminato) [((2- BuNO)CHCH)N] (TriNO )...
8.
Staun S, Wu G, Lukens W, Hayton T
Chem Sci . 2022 Jan; 12(47):15519-15527. PMID: 35003580
Reaction of [K(DME)][Th{(R)(SiMe H)}(NR)] (R = SiMe) with 1 equiv. of [U(NR)(NH)] (1) in THF, in the presence of 18-crown-6, results in formation of a bridged uranium-thorium nitride complex, [K(18-crown-6)(THF)][(NR)U(μ-N)Th(NR)]...
9.
Darago L, Boshart M, Nguyen B, Perlt E, Ziller J, Lukens W, et al.
J Am Chem Soc . 2021 May; 143(22):8465-8475. PMID: 34029482
We report the synthesis and characterization of the trinuclear 4d-4f compounds [Co(CMe)][(CMe)Ln(μ-S)Mo(μ-S)Ln(CMe)], (Ln = Y, Gd, Tb, Dy), containing the highly polarizable MoS bridging unit. UV-Vis-NIR diffuse reflectance spectra and...
10.
Lukens W, Booth C, Walter M
Dalton Trans . 2021 Feb; 50(7):2530-2535. PMID: 33522542
Significant orbital mixing is rare in lanthanide complexes because of the limited radial extent of the 4f orbitals, which results in a generally small stabilization due to 4f orbital interactions....