Vladimir N Nesterov

A yet-outstanding supramolecular chemistry challenge is isolation of novel varieties of stacked complexes with finely-tuned donor-acceptor bonding and optoelectronic properties, as herein reported for binary adducts comprising two different cyclic...

C2 hydrocarbon separation from methane represents a technological challenge for natural gas upgrading. Herein, we report a new metal-organic framework, [CuL(DEF)]·2DEF (; HL = 4,4',4″,4‴-((1,1',1″,1‴)-benzene-1,2,4,5-tetrayltetrakis(ethene-2,1-diyl))tetrabenzoic acid; DEF = ,-diethylformamide; UNT...

The fusion of tetrapyrroles with aromatic heterocycles constitutes a useful tool for manipulating their opto-electronic properties. In this work, the synthesis of naphthodithiophene-fused porphyrins was achieved through a Heck reaction-based...

A series of fluorinated antimony(V) porphyrins, SbTPP(OMe)·PF, SbTPP(OTFE)·PF, SbT(4F)PP(OMe)·PF, SbT(35F)PP(OMe)·PF, SbT(345F)PP(OMe)·PF, SbT(4CF)PP(OMe)·PF, SbT(35CF)PP(OMe)·PF, and SbT(35CF)PP(OTFE)·PF, have been synthesized with phenyl [P], 4-fluorophenyl [(4F)P], 3,5-difluorophenyl [(35F)P], 3,4,5-difluorophenyl [(345F)P], 4-trifluoromethylphenyl [(4CF)P], and...

Unsymmetric pentacenequinone-fused (cross-conjugated) and pentacene-fused (linear-conjugated) porphyrins were designed and synthesized. The cross-conjugated ( - ) and linear-conjugated ( - ) porphyrins displayed strikingly different sets of optical and electronic...

A three-component cascade reaction comprising cyclic ketones, arylamines, and benzoylmethylene malonates has been developed to access 4,5,6,7-tetrahydro-1-indoles. The reaction was achieved through cooperative enamine-Brønsted catalysis in high yields with wide...

Crystals of the title compound, CHN ·BF , were unexpectedly grown from crystallization attempts of [Pt(4,4'-bpy)](BF) [Smith (2019 ▸). , 188-215] using toluene and aceto-nitrile. The tetra-fluoro-borate anion and the...

To study the photophysical and redox properties as a function of -aryl units, a series of hypervalent phosphorus(V) porphyrins, PP(OMe)·PF, PMP(OMe)·PF, PDMP(OMe)·PF, P345TMP(OMe)·PF, and P246TMP(OMe)·PF, with phenyl (P), 4-methoxyphenyl (MP),...

A new synthetic method to fuse benzo[4,5]imidazo[2,1-]isoindole to the porphyrin periphery at the β,β-positions has been developed, and its impact on the aromaticity and electronic structures is investigated. Reactivity investigation...

Here we present the synthesis and characterization of a hybrid vanadium-organic coordination polymer with robust magnetic order, a Curie temperature of ∼110 K, a coercive field of ∼5 Oe at...