Thomas L Groy
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Explore the profile of Thomas L Groy including associated specialties, affiliations and a list of published articles.
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51
Citations
210
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Recent Articles
1.
Odella E, Fetherolf J, Secor M, DiPaola L, Dominguez R, Gonzalez E, et al.
J Phys Chem Lett
. 2024 Oct;
15(43):10835-10841.
PMID: 39436359
Bioinspired benzimidazole-phenol constructs with an intramolecular hydrogen bond connecting the phenol and the benzimidazole have been synthesized to study both proton-coupled electron transfer (PCET) and excited-state intramolecular proton transfer (ESIPT)...
2.
Mena M, Kim J, So S, Ben-Daat H, Porter T, Ghosh C, et al.
Inorg Chem
. 2022 Apr;
61(17):6438-6450.
PMID: 35438990
It was recently discovered that (PDI)Mn (PDI = pyridine diimine) exists as a superposition of low-spin Mn(II) that is supported by a PDI dianion and intermediate-spin Mn(II) that is antiferromagnetically...
3.
Odella E, Secor M, Elliott M, Groy T, Moore T, Hammes-Schiffer S, et al.
Chem Sci
. 2021 Oct;
12(38):12667-12675.
PMID: 34703552
Proton-coupled electron transfer (PCET) reactions depend on the hydrogen-bond connectivity between sites of proton donors and acceptors. The 2-(2'-hydroxyphenyl) benzimidazole (BIP) based systems, which mimic the natural Tyr-His190 pair of...
4.
Odella E, Mora S, Wadsworth B, Goings J, Gervaldo M, Sereno L, et al.
Chem Sci
. 2021 Jun;
11(15):3820-3828.
PMID: 34122850
Designing molecular platforms for controlling proton and electron movement in artificial photosynthetic systems is crucial to efficient catalysis and solar energy conversion. The transfer of both protons and electrons during...
5.
Pal R, Kim S, Lee W, Mena M, Khurshid A, Ghosh C, et al.
Inorg Chem
. 2021 May;
60(11):7708-7718.
PMID: 34008966
Refluxing Mo(CO) in the presence of the phosphine-functionalized α-diimine ligand DI allowed for substitution and formation of the dicarbonyl complex, (DI)Mo(CO). Oxidation with I followed by heating resulted in further...
6.
Oh C, Siewe J, Nguyen T, Kawamura A, Flores M, Groy T, et al.
Dalton Trans
. 2020 Oct;
49(41):14463-14474.
PMID: 33034607
The electronic structure of a dimeric manganese hydride catalyst supported by β-diketiminate ligands, [(2,6-iPr2PhBDI)Mn(μ-H)]2, was investigated with density functional theory. A triple bond between the manganese centres was anticipated from...
7.
Nguyen T, Kim J, Kim S, Oh C, Flores M, Groy T, et al.
Chem Commun (Camb)
. 2020 Mar;
56(28):3959-3962.
PMID: 32149290
The manganese hydride dimer, [(BDI)Mn(μ-H)], was found to mediate nitrile dihydroboration, rendering it the first manganese catalyst for this transformation. Stoichiometric experiments revealed that benzonitrile insertion affords [(BDI)Mn(μ-NCHCH)] en route...
8.
Vartak P, Wang Z, Groy T, Trovitch R, Wang R
ACS Omega
. 2020 Feb;
5(4):1949-1955.
PMID: 32039331
The addition of lead to diphenyl diselenide in ethylenediamine (en) or pyridine (py) allowed for the observation of the solvento complexes, (en)Pb(SePh) or (py)Pb(SePh), respectively. Performing this reaction in dimethyl...
9.
Ghosh C, Kim S, Mena M, Kim J, Pal R, Rock C, et al.
J Am Chem Soc
. 2019 Aug;
141(38):15327-15337.
PMID: 31462037
,-Diborylamines have emerged as promising reagents in organic synthesis; however, their efficient preparation and full synthetic utility have yet to be realized. To address both shortcomings, an effective catalyst for...
10.
Mukhopadhyay T, Flores M, Groy T, Trovitch R
Chem Sci
. 2018 Nov;
9(39):7673-7680.
PMID: 30393528
The dimeric β-diketiminate manganese hydride compound, [(BDI)Mn(μ-H)], was prepared by treating [(BDI)Mn(μ-Cl)] with NaEtBH. This compound was characterized by single crystal X-ray diffraction and found to feature high-spin Mn centres...