Thomas J Longo
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Explore the profile of Thomas J Longo including associated specialties, affiliations and a list of published articles.
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8
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14
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Recent Articles
1.
Longo T, Buldyrev S, Anisimov M, Caupin F
J Phys Chem B
. 2023 Mar;
127(13):3079-3090.
PMID: 36951605
It has been hypothesized that liquid polyamorphism, the existence of multiple amorphous states in a single-component substance, may be caused by molecular or supramolecular interconversion. A simple microscopic model [Caupin...
2.
Longo T, Shumovskyi N, Uralcan B, Buldyrev S, Anisimov M, Debenedetti P
Proc Natl Acad Sci U S A
. 2022 Dec;
120(1):e2215012120.
PMID: 36580588
The separation of substances into different phases is ubiquitous in nature and important scientifically and technologically. This phenomenon may become drastically different if the species involved, whether molecules or supramolecular...
3.
Fried N, Longo T, Anisimov M
J Chem Phys
. 2022 Sep;
157(10):101101.
PMID: 36109224
Fluid polyamorphism, the existence of multiple amorphous fluid states in a single-component system, has been observed or predicted in a variety of substances. A remarkable example of this phenomenon is...
4.
Shumovskyi N, Longo T, Buldyrev S, Anisimov M
Phys Rev E
. 2022 Aug;
106(1-2):015305.
PMID: 35974620
We suggest a simple model to describe polyamorphism in single-component fluids using a maximum-valence approach. The model contains three types of interactions: (i) Atoms attract each other by van der...
5.
Longo T, Anisimov M
J Chem Phys
. 2022 Mar;
156(8):084502.
PMID: 35232197
If a binary liquid mixture, composed of two alternative species with equal amounts, is quenched from a high temperature to a low temperature, below the critical point of demixing, then...
6.
Uralcan B, Longo T, Anisimov M, Stillinger F, Debenedetti P
J Chem Phys
. 2021 Dec;
155(20):204502.
PMID: 34852466
Liquid-liquid phase separation of fluids exhibiting interconversion between alternative states has been proposed as an underlying mechanism for fluid polyamorphism and may be of relevance to the protein function and...
7.
Shumovskyi N, Longo T, Buldyrev S, Anisimov M
Phys Rev E
. 2021 Jul;
103(6):L060101.
PMID: 34271768
A fluid composed of two molecular species may undergo phase segregation via spinodal decomposition. However, if the two molecular species can interconvert, e.g., change their chirality, then a phenomenon of...
8.
Zhang S, Cui P, Liu T, Wang Q, Longo T, Thierer L, et al.
Angew Chem Int Ed Engl
. 2020 May;
59(35):15215-15219.
PMID: 32441448
Despite their connection to ammonia synthesis, little is known about the ability of iron-bound, bridging nitrides to form N-H bonds. Herein we report a linear diiron bridging nitride complex supported...