Stephen M Holmes
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Explore the profile of Stephen M Holmes including associated specialties, affiliations and a list of published articles.
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22
Citations
76
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Recent Articles
1.
Yang J, You M, Liu S, Deng Y, Chang X, Holmes S, et al.
Inorg Chem
. 2023 Oct;
62(42):17530-17536.
PMID: 37801447
Extending a selected cyanometalate block into a higher dimensional framework continues to present intriguing challenges in the fields of chemistry and material science. Here, we prepared two rope-like chain compounds...
2.
Meng L, Deng Y, Holmes S, Zhang Y
Dalton Trans
. 2023 Jan;
52(6):1616-1622.
PMID: 36648100
Recently, a family of [FeCo] molecular capsules that display tunable electron transfer-coupled spin transition (ETCST) behavior were reported a smart approach through Schiff-base condensation of aldehyde-functionalized 2,2-bipyridines (bpy) and 1,7-heptanediamine...
3.
Zhang Y, Ferko P, Siretanu D, Ababei R, Rath N, Shaw M, et al.
J Am Chem Soc
. 2014 Oct;
136(48):16854-64.
PMID: 25340715
Two structurally related and photoresponsive cyanide-bridged Fe/Co square complexes, {Fe2Co2}, are reported: {[(Tp(Me))Fe(CN)3]2[Co(bpy)2]2[(Tp(Me))Fe(CN)3]2}·12H2O (2) and {[(Tp(Me))Fe(CN)3]2[Co(bpy)2]2[BPh4]2}·6MeCN (3), where Tp(Me) and bpy are hydridotris(3-methylpyrazol-1-yl)borate and 2,2'-bipyridine, respectively. Through electrochemical and spectroscopic...
4.
Panja A, Guionneau P, Jeon I, Holmes S, Clerac R, Mathoniere C
Inorg Chem
. 2012 Nov;
51(22):12350-9.
PMID: 23134343
A new symmetrical tricyanide building block mer-[Fe(bbp)(CN)3](2-) [1; bbp = bis(2-benzimidazolyl)pyridine dianion] has been prepared and structurally and magnetically characterized. It forms a new low-spin meridionally capped {Fe(III)L(CN)3} fragment with...
5.
Zhang Y, Mallik U, Rath N, Clerac R, Holmes S
Inorg Chem
. 2011 Sep;
50(21):10537-9.
PMID: 21950315
A new tricyanoferrate(III) building block and a trinuclear single-molecule magnet derivative are described. The treatment of a 2:1 ratio of [NEt(4)][(Tp*(Bn))Fe(III)(CN)(3)]·H(2)O·MeOH [1; Tp*(Bn) = tris(3,5-dimethyl-4-benzyl)pyrazolylborate] with nickel(II) trifluoromethanesulfonate gives {[(Tp*(Bn))Fe(III)(CN)(3)](2)[Ni(II)(DMF)(4)]}·2DMF...
6.
Siretanu D, Li D, Buisson L, Bassani D, Holmes S, Mathoniere C, et al.
Chemistry
. 2011 Sep;
17(42):11704-8.
PMID: 21905143
No abstract available.
7.
Zhang Y, Mallik U, Clerac R, Rath N, Holmes S
Chem Commun (Camb)
. 2011 Jun;
47(25):7194-6.
PMID: 21625681
Two cyano-bridged single-molecule magnets of {Fe(III)(4)Ni(II)(2)} and {Fe(III)(6)Ni(II)(3)} stoichiometry are described via their magnetic properties described in the frame of geometrical core distortions and orientations of their local anisotropy axes.
8.
Synthesis and characterization of di- and trivalent pyrazolylborate β-diketonates and cyanometalates
Tang M, Li D, Mallik U, Zhang Y, Clerac R, Yee G, et al.
Inorg Chem
. 2011 Apr;
50(11):5153-64.
PMID: 21520919
The syntheses, structures, and magnetic properties of a series of di- and trivalent hydridotris(3,5-dimethylpyrazol-1-yl)borate (Tp*) cyanomanganates are described. Treatment of tris(acetylacetonate)manganese(III) [Mn(acac)(3)] with KTp* and tetra(ethyl)ammonium cyanide affords [NEt(4)][(Tp*)Mn(II)(κ(2)-acac)(CN)] (1),...
9.
Zhang Y, Mallik U, Rath N, Yee G, Clerac R, Holmes S
Chem Commun (Camb)
. 2010 Jun;
46(27):4953-5.
PMID: 20526498
A new low symmetry octanuclear cyano-based {Fe(III)(4)Ni(II)(4)} single-molecule magnet (SMM) is described. This SMM exhibits the highest energy barrier (Delta/k(B) approximately 33 K) for magnetization reversal seen for any first-row...
10.
Tang M, Li D, Mallik U, Withers J, Brauer S, Rhodes M, et al.
Inorg Chem
. 2010 May;
49(11):4753-5.
PMID: 20438094
Treatment of tris(3-cyano-2,4-pentanedionato)manganese(III) with KTp*, followed by [NEt(4)]CN affords [NEt(4)][(Tp*)Mn(III)(CN)(3)] (1); subsequent treatment of 1 with divalent triflates (OTf) and 2,2'-bipyridine (bpy) affords {Mn(III)(2)M(II)(2)} complexes (M(II) = Mn, 2; Ni,...