Simon Duttwyler
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Explore the profile of Simon Duttwyler including associated specialties, affiliations and a list of published articles.
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38
Citations
243
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Recent Articles
1.
Sun W, Jin Y, Wang Y, Wen Z, Sun J, Yao J, et al.
Chem Sci
. 2025 Mar;
PMID: 40060093
Highly regioselective B(12) substitutions of the monocarborane anion [CBH] has been a challenge. Here, we synthesized a stable B-O-N zwitterionic compound with an impressive yield (isolated yield up to 98%)...
2.
Zhang K, Feng L, Jin Y, Liu J, Duttwyler S
Chem Commun (Camb)
. 2025 Feb;
61(20):4026-4029.
PMID: 39950928
A σ,π-bis(copper) acetylide complex, (CBH-12-CC)Cu(PiPr) (2), enables the formation of regioselective 1,4-disubstituted 1,2,3-triazoles containing monocarborane anion [CBH] CuAAC with organic azides under mild conditions. This method achieves 1,2,3-triazolylated monocarboranes (3)...
3.
Zhang K, Cao K, Sun J, Jin Y, Liu J, Duttwyler S
Inorg Chem
. 2024 Aug;
63(36):16595-16599.
PMID: 39177198
We report the first crystal structure of heteroleptic Grignard reagent based on the carborane / dianion [CBH-12-C≡C]. Full characterization reveals a rare coordination pattern and affirms the bimetallic nature. Navigating...
4.
Lin C, Jin Y, Sun J, Ye Z, Chen T, Liu J, et al.
Dalton Trans
. 2023 Aug;
52(32):11042-11046.
PMID: 37540047
Penta-iodination of the B2-6 positions of the {CB} monocarborane cluster is reported. Products of the structure [2,3,4,5,6-I-CBH-12-X] (X = H, Me, Et, Ph, Br, I) were obtained and fully characterized....
5.
Jin Y, Sun J, Zhang K, Liu J, Worle M, Duttwyler S
Chem Commun (Camb)
. 2022 Dec;
59(1):67-70.
PMID: 36453249
Regioselective, five-fold B-H activation of the monocarborane cluster [CBH] at the positions B7-11 has been accomplished. Selective substitution of these positions by B-H activation has not been reported before. Our...
6.
Hamdaoui M, Liu F, Cornaton Y, Lu X, Shi X, Zhang H, et al.
J Am Chem Soc
. 2022 Sep;
144(40):18359-18374.
PMID: 36173688
Exploration of new organometallic systems based on polyhedral boron clusters has the potential to solve challenging chemical problems such as the stabilization of reactive intermediates and transition-state-like species postulated for...
7.
Liu F, Chen T, Zhang K, Jiang T, Liu J, Duttwyler S
Dalton Trans
. 2022 Jun;
51(29):10880-10886.
PMID: 35770696
The Sonogashira cross coupling between the monocarborane cluster 12-ethynylmonocarba--dodecaborate [CBH-12-CCH] and bromoarenes under Pd catalysis has been developed, providing access to aryl carboranyl alkynes in yields of 42-95%. The transformations...
8.
Shen Y, Zheng K, Dontha R, Pan Y, Liu J, Duttwyler S
RSC Adv
. 2022 May;
8(40):22447-22451.
PMID: 35539747
The preparation of the carborane acid chloride [1-(COCl)-CBH] from the carboxylic acid [1-(COOH)-CBH] is reported. This acid chloride exhibits remarkable inertness towards moisture and can be stored under ambient conditions...
9.
Varkhedkar R, Yang F, Dontha R, Zhang J, Liu J, Spingler B, et al.
ACS Cent Sci
. 2022 Mar;
8(3):322-331.
PMID: 35350606
The identification of an alternative chemical space in order to address the global challenge posed by emerging antimicrobial resistance is very much needed for the discovery of novel antimicrobial lead...
10.
Jiang Y, Hu J, Wang L, Sun W, Xu N, Krishna R, et al.
Angew Chem Int Ed Engl
. 2022 Feb;
61(18):e202200947.
PMID: 35199908
Propyne/propylene (C H /C H ) separation is an important but challenging industrial process to produce polymer-grade C H and recover high-purity C H . Herein, we report an ultrastable...