S Skanthakumar
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Explore the profile of S Skanthakumar including associated specialties, affiliations and a list of published articles.
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Articles
42
Citations
131
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Recent Articles
1.
Skanthakumar S, Yu X, Autschbach J, Soderholm L
Inorg Chem
. 2023 Sep;
62(39):15891-15901.
PMID: 37721450
BaPuO and SrPuO were synthesized, and their structures were refined in the orthorhombic space group , a common distortion from the classic 3̅ cubic perovskite. Magnetic-susceptibility measurements, obtained as a...
2.
Servis M, Piechowicz M, Skanthakumar S, Soderholm L
Phys Chem Chem Phys
. 2021 Apr;
23(14):8880-8890.
PMID: 33876047
The molecular and nanoscale origins of nonideality in excess thermodynamic properties are essential to understanding cosolvent mixtures, yet they remain challenging to determine. Here, we consider a binary mixture of...
3.
Piechowicz M, Chiarizia R, Skanthakumar S, Rowan S, Soderholm L
Chemphyschem
. 2020 May;
21(11):1157-1165.
PMID: 32363763
Polymerized high internal phase emulsions (poly(HIPE)s) are porous polymer monoliths whose synthesis can easily be tailored to allow incorporation of functional units. In this work, nitrile containing poly(HIPE)s have been...
4.
Jin G, Malliakas C, Hu Y, Booth C, Ibers J, Sokaras D, et al.
Angew Chem Int Ed Engl
. 2019 Sep;
58(45):16130-16133.
PMID: 31549462
A new binary compound, NpSe possesses metal-chalcogen and chalcogen-chalcogen interactions different from those reported for other metal dichalcogenides. Its structure is incommensurately modulated and features linear Se chains and valence-ambiguous...
5.
Qiao B, Skanthakumar S, Soderholm L
J Chem Theory Comput
. 2018 Feb;
14(3):1781-1790.
PMID: 29438613
The accurate understanding of metal ion hydration in solutions is a prerequisite for predicting stability, reactivity, and solubility. Herein, additive CHARMM force field parameters were developed to enable molecular dynamics...
6.
Jin G, Lin J, Estes S, Skanthakumar S, Soderholm L
J Am Chem Soc
. 2017 Nov;
139(49):18003-18008.
PMID: 29148745
The influence of countercations (A) in directing the composition of monomeric metal-ligand (ML) complexes that precipitate from solution are often overlooked despite the wide usage of A in materials synthesis....
7.
Skanthakumar S, Jin G, Lin J, Vallet V, Soderholm L
J Phys Chem B
. 2017 Aug;
121(36):8577-8584.
PMID: 28817281
Seeking predictive insights into how metal-ion speciation impacts solution chemistry as well as the composition and structure of solid-precipitates, thorium correlations, with both solvent and other solute ions, were quantitatively...
8.
Knope K, Skanthakumar S, Soderholm L
Inorg Chem
. 2015 Oct;
54(21):10192-6.
PMID: 26460785
We report the room temperature synthesis and structural characterization of a μ2-hydroxo-bridged Pu(IV) dimer obtained from an acidic nitric acid solution. The discrete Pu2(OH)2(NO3)6(H2O)4 moiety crystallized with two distinct crystal...
9.
Kalaji A, Skanthakumar S, Kanatzidis M, Mitchell J, Soderholm L
Inorg Chem
. 2014 May;
53(12):6321-8.
PMID: 24871556
The relationship of solution speciation and the structures of corresponding precipitates is examined for an aqueous Hf(4+) sulfate series. High-energy X-ray scattering (HEXS) and Raman spectroscopy data are used to...
10.
Polinski M, Garner 3rd E, Maurice R, Planas N, Stritzinger J, Parker T, et al.
Nat Chem
. 2014 Apr;
6(5):387-92.
PMID: 24755589
The participation of the valence orbitals of actinides in bonding has been debated for decades. Recent experimental and computational investigations demonstrated the involvement of 6p, 6d and/or 5f orbitals in...