Richard J Staples
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Explore the profile of Richard J Staples including associated specialties, affiliations and a list of published articles.
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160
Citations
470
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Recent Articles
21.
Singh J, Staples R, Shreeve J
Org Lett
. 2023 Aug;
25(32):6082-6086.
PMID: 37556303
Hydrogen bonds (H-bonds) in energetic compounds have a very pronounced effect on physicochemical properties such as density, thermal stability, sensitivity, and solubility. Now a strategy to synthesize nitrogen-rich energetic materials...
22.
Lal S, Staples R, Shreeve J
Org Lett
. 2023 Jul;
25(27):5100-5104.
PMID: 37409774
A straightforward synthetic strategy for newly designed nitrogen-rich planar explosives and solid propellants is reported. These materials exhibit high densities (1.69-1.95 g cm), high positive enthalpies of formation (approaching 1149.21...
23.
Ghosh P, Stauffer M, Ahmed M, Bertke J, Staples R, Warren T
J Am Chem Soc
. 2023 May;
145(22):12007-12012.
PMID: 37224264
Reduction of nitrate is an essential, yet challenging chemical task required to manage this relatively inert oxoanion in the environment and biology. We show that thiols, ubiquitous reductants in biology,...
24.
Sielaff E, Staples R, Biros S
Acta Crystallogr E Crystallogr Commun
. 2023 Apr;
79(Pt 4):345-348.
PMID: 37057017
The mol-ecular structure of -butyl 3,6-di-iodo-carbazole-9-carboxyl-ate, CHINO, features a nearly planar 13-membered carbazole ring with C-I bond lengths of 2.092 (4) and 2.104 (4) Å. The carbamate group has key...
25.
Parkin S, Cunningham J, Rawls B, Bender J, Staples R, Biros S
Acta Crystallogr E Crystallogr Commun
. 2023 Apr;
79(Pt 4):246-253.
PMID: 37057016
This paper compares variations on a structure model derived from an X-ray diffraction data set from a solid solution of chalcogenide derivatives of -1,2-bis-(di-phenyl-phosphan-yl)ethyl-ene, namely, 1,2-(ethene-1,2-di-yl)bis-(di-phenyl-phoshpine sulfide/selenide), CHPSSe. A sequence...
26.
Chinnam A, Staples R, Shreeve J
Org Lett
. 2023 Feb;
25(9):1481-1485.
PMID: 36847214
In this study, a simple synthetic strategy for bridged bis(nitramide)-based -substituted tetrazoles is described. All new compounds were isolated and fully characterized by sophisticated analytical techniques. The structures of the...
27.
Lal S, Staples R, Shreeve J
Dalton Trans
. 2023 Feb;
52(11):3449-3457.
PMID: 36825979
A variety of phenylene-bridged isoxazole and tetrazole-1-ol based green energetic materials was synthesized, for the first time, in good to excellent yields. The structures of the newly synthesized compounds were...
28.
Rawls B, Cunningham J, Bender J, Staples R, Biros S
Acta Crystallogr E Crystallogr Commun
. 2023 Jan;
79(Pt 1):28-32.
PMID: 36628368
The crystal structures of ()-(ethene-1,2-di-yl)bis-(di-phenyl-phosphine sulfide), CHPS (), along with its complex with Pt dichloride, di-chlorido[()-(ethene-1,2-di-yl)bis-(di-phenyl-phosphine sulfide)-κ ,']platinum(II), [PtCl(CHPS)] (), are described here. Compound features P=S bond lengths of 1.9571 ...
29.
Raithel A, Meador W, Kim T, Staples R, Delcamp J, Hamann T
J Am Chem Soc
. 2023 Jan;
145(2):1367-1377.
PMID: 36595559
Strong-field hexadentate ligands were synthesized and coordinated to cobalt metal centers to result in three new low-spin to low-spin Co(III/II) redox couples. The ligand backbone has been modified with dimethyl...
30.
Singh J, Staples R, Shreeve J
Org Lett
. 2022 Nov;
24(48):8832-8836.
PMID: 36410011
By integrating two approaches─an ethene bridge to enhance safety and planarity to support good density─we have achieved new high-energy-density materials -. Compounds - show good detonation performance ( = 8037-9305...