Raphael Buhler
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Explore the profile of Raphael Buhler including associated specialties, affiliations and a list of published articles.
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9
Citations
17
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Recent Articles
1.
Buhler R, Schutz M, Andriani K, Quiles M, de Mendonca J, Ocampo-Restrepo V, et al.
Nat Chem
. 2025 Jan;
PMID: 39849109
The exploration of ligated metal clusters' chemical space is challenging, partly owing to an insufficiently targeted access to reactive clusters. Now, dynamic mixtures of clusters, defined as living libraries, are...
2.
Cribbin L, Twamley B, Buga N, O Brien J, Buhler R, Fischer R, et al.
Beilstein J Org Chem
. 2024 Nov;
20:2784-2798.
PMID: 39530078
Unlike their planar counterparts, classic synthetic protocols for C-C bond forming reactions on nonplanar porphyrins are underdeveloped. The development of C-C bond forming reactions on nonplanar porphyrins is critical in...
3.
Buhler R, Wolf R, Gemel C, Stephan J, Deger S, Kahlal S, et al.
Inorg Chem
. 2024 Sep;
63(38):17617-17625.
PMID: 39253905
The properties of cuprophilic compounds and the underlying fundamental principles responsible for the Cu(I)···Cu(I) interactions have been the subject of intense research as their diverse structural and physical attributes are...
4.
Buhler R, Weininger R, Stephan J, Muhr M, Bock B, Gemel C, et al.
Dalton Trans
. 2024 Apr;
53(42):17162-17168.
PMID: 38687113
Reaction of neutral olefin complexes of ruthenium and molybdenum with GaTMP (TMP = 2,2,6,6-tetramethylpiperidinyl) by substitution leads to the formation of respective five- and six-coordinated homoleptic products. [Ru(GaTMP)] (1) and...
5.
Antsiburov I, Schutz M, Buhler R, Muhr M, Stephan J, Gemel C, et al.
Inorg Chem
. 2024 Feb;
63(8):3749-3756.
PMID: 38335041
Key strategies in cluster synthesis include the use of modulating agents (e.g., coordinating additives). We studied the influence of various phosphines exhibiting different steric and electronic properties on the reduction...
6.
Benzene-1,4-Di(dithiocarboxylate) Linker-Based Coordination Polymers of Mn, Zn, and Mixed-Valence Fe
Aust M, Schonherr M, Halter D, Schrock L, Pickl T, Deger S, et al.
Inorg Chem
. 2023 Dec;
63(1):129-140.
PMID: 38109782
Three new coordination polymers (CPs) constructed from the linker 1,4-di(dithiocarboxylate) (BDDTC)─the sulfur-analog of 1,4-benzenedicarboxylate (BDC)─together with Mn-, Zn-, and Fe-based inorganic SBUs are reported with description of their structural and...
7.
Buhler R, Muhr M, Stephan J, Wolf R, Schutz M, Gemel C, et al.
Dalton Trans
. 2023 Jul;
52(31):10905-10910.
PMID: 37489254
Irradiation of [Ru(GaCp*)(SiEt)H] (1) at 350 nm induces reductive elimination of dihydrogen and triethylsilane and generates unsaturated Ru/Ga species. This photochemically induced cascading reductive elimination processes generate the reactive intermediate...
8.
Muhr M, Liang H, Allmendinger L, Buhler R, Napoli F, Ukaj D, et al.
Angew Chem Int Ed Engl
. 2023 Jul;
62(36):e202308790.
PMID: 37408378
The bimetallic, decanuclear Ni Ga -cluster of the formula [Ni (GaTMP) (μ -GaTMP) (μ -GaTMP)] (1, TMP=2,2,6,6-tetramethylpiperidinyl) reacts reversibly with dihydrogen under the formation of a series of (poly-)hydride clusters...
9.
Muhr M, Buhler R, Liang H, Gilch J, Jandl C, Kahlal S, et al.
Chemistry
. 2022 Jun;
28(54):e202200887.
PMID: 35748293
Treatment of [Ru(COD)(MeAllyl) ] and [Ru(COD)(COT)] with GaCp* under hydrogenolytic conditions leads to reactive intermediates which activate Si-H or C-H bonds, respectively. The product complexes [Ru(GaCp*) (SiEt )H ] (1)...
10.
Muhr M, Heiss P, Schutz M, Buhler R, Gemel C, Linden M, et al.
Dalton Trans
. 2021 May;
50(26):9031-9036.
PMID: 33970171
A new setup combining a ThermoFisher Exactive Plus Orbitrap Mass Spectrometer with a liquid injection field desorption ionization (LIFDI) source directly connected to an inert atmosphere glovebox is presented. The...