Radek Marek
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Explore the profile of Radek Marek including associated specialties, affiliations and a list of published articles.
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98
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610
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Recent Articles
1.
Jurcek O, Chattopadhyay S, Kalenius E, Linnanto J, Kiesila A, Jurcek P, et al.
Angew Chem Int Ed Engl
. 2024 Jun;
63(36):e202409134.
PMID: 38845398
Nature uses various chiral and unsymmetric building blocks to form substantial and complex supramolecular assemblies. In contrast, the majority of organic ligands used in metallosupramolecular chemistry are symmetric and achiral....
2.
Mechanisms of Ligand Hyperfine Coupling in Transition-Metal Complexes: σ and π Transmission Pathways
Novotny J, Munzarova M, Marek R
Inorg Chem
. 2024 May;
63(19):8580-8592.
PMID: 38690843
Theoretical interpretation of hyperfine interactions was pioneered in the 1950s-1960s by the seminal works of McConnell, Karplus, and others for organic radicals and by Watson and Freeman for transition-metal (TM)...
3.
Novotny J, Komorovsky S, Marek R
Acc Chem Res
. 2024 Apr;
57(10):1467-1477.
PMID: 38687879
ConspectusMagnetic resonance techniques represent a fundamental class of spectroscopic methods used in physics, chemistry, biology, and medicine. Electron paramagnetic resonance (EPR) is an extremely powerful technique for characterizing systems with...
4.
Kumar P, Rautiainen J, Novotny J, Ward J, Marek R, Rissanen K, et al.
Chemistry
. 2023 Dec;
30(13):e202303643.
PMID: 38055221
The coordination nature of 2-mono- and 2,6-disubstituted pyridines with electron-withdrawing halogen and electron-donating methyl groups for [N-X-N] (X=I, Br) complexations have been studied using N NMR, X-ray crystallography, and Density...
5.
Pikulova P, Misenkova D, Marek R, Komorovsky S, Novotny J
J Chem Theory Comput
. 2023 Mar;
19(6):1765-1776.
PMID: 36896579
Understanding how the electronic g-tensor is linked to the electronic structure is desirable for the correct interpretation of electron paramagnetic resonance spectra. For heavy-element compounds with large spin-orbit (SO) effects,...
6.
Chyba J, Hruzikova A, Knor M, Pikulova P, Markova K, Novotny J, et al.
Inorg Chem
. 2023 Feb;
62(8):3381-3394.
PMID: 36763803
In recent decades, transition-metal coordination compounds have been extensively studied for their antitumor and antimetastatic activities. In this work, we synthesized a set of symmetric and asymmetric Ru(III) and Rh(III)...
7.
Cuyacot B, Novotny J, Berger R, Komorovsky S, Marek R
Chemistry
. 2022 Apr;
28(24):e202200966.
PMID: 35411974
Radek Marek and his co-workers at Masaryk University, Brno, Czechia have been invited to prepare the cover of this issue. The image depicts the relativistic spin-orbit coupling that is associated...
8.
Cuyacot B, Novotny J, Berger R, Komorovsky S, Marek R
Chemistry
. 2022 Mar;
28(24):e202200277.
PMID: 35229922
Relativistic effects are known to alter the chemical bonds and spectroscopic properties of heavy-element compounds. In this work, we introduce the concept of spin-orbit (SO) electronegativity of a heavy atom,...
9.
Sojka M, Chyba J, Paul S, Wawrocka K, Honigova K, Cuyacot B, et al.
Inorg Chem
. 2021 Nov;
60(23):17911-17925.
PMID: 34738800
Platinum-based anticancer drugs are actively developed utilizing lipophilic ligands or drug carriers for the efficient penetration of biomembranes, reduction of side effects, and tumor targeting. We report the development of...
10.
Novotny A, Novotny J, Kejnovska I, Vorlickova M, Fiala R, Marek R
Nucleic Acids Res
. 2021 Oct;
49(20):11425-11437.
PMID: 34718718
Non-canonical forms of nucleic acids represent challenging objects for both structure-determination and investigation of their potential role in living systems. In this work, we uncover a structure adopted by GA...