Philipp Dabringhaus
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Explore the profile of Philipp Dabringhaus including associated specialties, affiliations and a list of published articles.
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7
Citations
16
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Recent Articles
1.
Roehner D, Ramos E, Dabringhaus P, Scherer H, Krossing I
Chemistry
. 2025 Jan;
31(11):e202403959.
PMID: 39777928
The bonding situation in [Fp-P][Al(OR)] (1) (Fp = (CO)CpFe, R = C(CF)) gives rise to an Umpolung of the P fragment, which should make it accessible for nucleophiles. To investigate...
2.
Dabringhaus P, Molino A, Gilliard Jr R
J Am Chem Soc
. 2024 Sep;
146(39):27186-27195.
PMID: 39298432
Low-valent antimony and bismuth have emerged as novel platforms for achieving reversible small-molecule activation at main-group metals. Although various examples of oxidative addition reactions at monomeric Sb(I) and Bi(I) have...
3.
Dabringhaus P, Heizmann T, Krossing I
Chemistry
. 2023 Aug;
29(58):e202302212.
PMID: 37583347
Although the discovery of the Ga complex salt [Ga(PhF) ][Al(OR ) ] (R =C(CF ) , PhF=C H F) invoked the preparation of a diverse library of cationic Ga(I) coordination...
4.
Dabringhaus P, Zedlitz S, Krossing I
Chem Commun (Camb)
. 2022 Dec;
59(2):187-190.
PMID: 36484783
Unique π-cyclopentadienyl bridged dialanes are synthesized as complex salts with aluminate anions by comproportionation of aluminocenium cations [Al(Cp)(Cp*)]/[AlCp] with [(AlCp*)]. Very short Al-Al bond lengths occur in positively charged Al...
5.
Dabringhaus P, Zedlitz S, Giarrana L, Scheschkewitz D, Krossing I
Angew Chem Int Ed Engl
. 2022 Dec;
62(8):e202215170.
PMID: 36479813
Schnöckel's [(AlCp*) ] and Jutzi's [SiCp*][B(C F ) ] (Cp*=C Me ) are landmarks in modern main-group chemistry with diverse applications in synthesis and catalysis. Despite the isoelectronic relationship between...
6.
Dabringhaus P, Krossing I
Chem Sci
. 2022 Nov;
13(41):12078-12086.
PMID: 36349105
AlCp*-complexes with transition metals have shown to be highly reactive and enable C-H or Si-H bond activation. Yet, complexes of AlCp* with low-valent main-group metals are scarce. Here, we report...
7.
Dabringhaus P, Willrett J, Krossing I
Nat Chem
. 2022 Aug;
14(10):1151-1157.
PMID: 35927330
Low-valent aluminium compounds are very reactive main-group species and have therefore been widely investigated. Since the isolation of a stable molecular Al(I) compound in 1991, [(AlCp*)] (Cp* = [CMe]), a...
8.
Dabringhaus P, Schorpp M, Scherer H, Krossing I
Angew Chem Int Ed Engl
. 2020 Aug;
59(49):22023-22027.
PMID: 32776669
The potential of a dicationic strontium ansa-arene complex for Lewis acid catalysis has been explored. The key to its synthesis was a simple salt metathesis from SrI and 2 Ag[Al(OR...