Max Malacria
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Explore the profile of Max Malacria including associated specialties, affiliations and a list of published articles.
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Recent Articles
11.
Lacote E, Delouvrie B, Fensterbank L, Malacria M
Angew Chem Int Ed Engl
. 2018 May;
37(15):2116-2118.
PMID: 29711040
Alkylidene-substituted cyclopentane derivatives are formed in high enantiomeric purity by the reaction shown below. A highly diastereoselective radical cyclization is followed by elimination of a β-sulfinyl radical. Interestingly, the addition...
12.
Wang Y, Monfredini A, Deyris P, Blanchard F, Derat E, Maestri G, et al.
Chem Sci
. 2017 Nov;
8(11):7394-7402.
PMID: 29163890
We present that cationic rings can act as donor ligands thanks to suitably delocalized metal-metal bonds. This could grant parent complexes with the peculiar properties of aromatic rings that are...
13.
Maestri G, Caneque T, Ca N, Derat E, Catellani M, Chiusoli G, et al.
Org Lett
. 2016 Dec;
18(23):6108-6111.
PMID: 27934378
A method to obtain aryl nitriles from the corresponding halides by Pd catalysis, in the absence of any cyanide source, is reported. The reaction of an aryl halide, ethyl nitroacetate,...
14.
Monfredini A, Santacroce V, Deyris P, Maggi R, Bigi F, Maestri G, et al.
Dalton Trans
. 2016 Jul;
45(40):15786-15790.
PMID: 27396973
Highly symmetric [Pd] clusters that present delocalized metal-metal bonds can catalyse the selective semi-reduction of internal alkynes to cis-alkenes. Studies on factors governing the formation of all-metal aromatics enabled the...
15.
Caneque T, Gomes F, Mai T, Maestri G, Malacria M, Rodriguez R
Nat Chem
. 2015 Aug;
7(9):744-51.
PMID: 26291947
Anthracyclines such as doxorubicin are used extensively in the treatment of cancers. Anthraquinone-related angucyclines also exhibit antiproliferative properties and have been proposed to operate via similar mechanisms, including direct genome...
16.
Wang Y, Deyris P, Caneque T, Blanchard F, Li Y, Bigi F, et al.
Chemistry
. 2015 Jul;
21(35):12271-4.
PMID: 26149891
A simple synthetic method allows the one-pot assembly of C3 -symmetric, 44-core-valence-electron, triangular Pd or Pt clusters and their heterobimetallic mixed Pd/Pt analogues. These mixed metal complexes are the first...
17.
Brazel C, Dupre N, Malacria M, Hasenknopf B, Lacote E, Thorimbert S
Chemistry
. 2014 Oct;
20(49):16074-7.
PMID: 25345788
An α1 -Dawson polyanion bearing a lateral side chain with a 4-aminopyridine end group was synthesized. This organopolyoxometalate catalyzes the addition of indenyl allyl silanes to cinnamoyl fluorides. The polyanionic...
18.
Fensterbank L, Malacria M
Acc Chem Res
. 2014 Feb;
47(3):953-65.
PMID: 24564512
Over the last two decades, electrophilic catalysis relying on platinum(II), gold(I), and gold(III) salts has emerged as a remarkable synthetic methodology. Chemists have discovered a large variety of organic transformations...
19.
Blanchard S, Fensterbank L, Gontard G, Lacote E, Maestri G, Malacria M
Angew Chem Int Ed Engl
. 2014 Jan;
53(7):1987-91.
PMID: 24453192
The first C3 -symmetric 44-core-valence-electron triangular palladium clusters, [{(SAr')(PAr3 )Pd}3 ](+) , have been synthesized by activation of the CS bond of isothioureas. Owing to delocalized metal-metal bonding, these stable...
20.
Narbonne V, Retailleau P, Maestri G, Malacria M
Org Lett
. 2014 Jan;
16(2):628-31.
PMID: 24380587
Joint palladium/norbornene organometallic catalysis allows for straightforward access to dibenzo[c,e]azepines. These synthetically challenging polycyclic frameworks form in one pot via a three-component coupling of an aryl iodide, a bromobenzylamine, and...