Matthew E OReilly
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Explore the profile of Matthew E OReilly including associated specialties, affiliations and a list of published articles.
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13
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89
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Recent Articles
1.
Kim R, Wegener E, Yang M, OReilly M, Oh S, Hendon C, et al.
J Am Chem Soc
. 2020 Nov;
142(49):20631-20639.
PMID: 33231440
High-valent Pd complexes are potent agents for the oxidative functionalization of inert C-H bonds, and it was previously shown that rapid electrocatalytic methane monofunctionalization could be achieved by electro-oxidation of...
2.
OReilly M, Kim R, Oh S, Surendranath Y
ACS Cent Sci
. 2017 Dec;
3(11):1174-1179.
PMID: 29202019
Electrophilic high-valent metal ions are potent intermediates for the catalytic functionalization of methane, but in many cases, their high redox potentials make these intermediates difficult or impossible to access using...
3.
OReilly M, Dutta S, Veige A
Chem Rev
. 2016 Jul;
116(14):8105-45.
PMID: 27366938
This review describes organometallic compounds and materials that are capable of mediating a rarely encountered but fundamentally important reaction: β-alkyl elimination at the metal-Cα-Cβ-R moiety, in which an alkyl group...
4.
Joglekar M, Nguyen V, Pylypenko S, Ngo C, Li Q, OReilly M, et al.
J Am Chem Soc
. 2015 Oct;
138(1):116-25.
PMID: 26492385
Low-temperature direct methane fuel cells (DMEFCs) offer the opportunity to substantially improve the efficiency of energy production from natural gas. This study focuses on the development of well-defined platinum organometallic...
5.
Nadif S, OReilly M, Ghiviriga I, Abboud K, Veige A
Angew Chem Int Ed Engl
. 2015 Oct;
54(50):15138-42.
PMID: 26490833
A chemically non-innocent pyrrole-based trianionic (ONO)(3-) pincer ligand within [(pyr-ONO)TiCl(thf)2 ] (2) can access the dianionic [(3H-pyr-ONO)TiCl2 (thf)] (1-THF) and monoanionic [(3H,4H-pyr-ONO)TiCl2 (OEt2 )][B{3,5-(CF3 )2 C6 H3 }4 ] (3-Et2...
6.
Fu R, OReilly M, Nielsen R, Goddard 3rd W, Gunnoe T
Chemistry
. 2014 Nov;
21(3):1286-93.
PMID: 25418788
A series of rhodium(III) bis(quinolinyl)benzene (bisq(x)) complexes was studied as candidates for the homogeneous partial oxidation of methane. Density functional theory (DFT) (M06 with Poisson continuum solvation) was used to...
7.
OReilly M, Fu R, Nielsen R, Sabat M, Goddard 3rd W, Gunnoe T
J Am Chem Soc
. 2014 Oct;
136(42):14690-3.
PMID: 25303016
Traditional C-H bond activation by a concerted metalation-deprotonation (CMD) mechanism involves precoordination of the C-H bond followed by deprotonation from an internal base. Reported herein is a "through-arene" activation of...
8.
OReilly M, Veige A
Chem Soc Rev
. 2014 Jun;
43(17):6325-69.
PMID: 24927219
Trianionic pincer and pincer-type ligands are the focus of this review. Metal ions from across the periodic table, from main group elements, transition metals, and the rare earths, are combined...
9.
OReilly M, Pahls D, Webb J, Boaz N, Majumdar S, Hoff C, et al.
Dalton Trans
. 2014 Apr;
43(22):8273-81.
PMID: 24715057
Net reductive elimination (RE) of MeX (X = halide or pseudo-halide: Cl(-), CF3CO2(-), HSO4(-), OH(-)) is an important step during Pt-catalyzed hydrocarbon functionalization. Developing Rh(I/III)-based catalysts for alkane functionalization is...
10.
OReilly M, Ghiviriga I, Abboud K, Veige A
Dalton Trans
. 2013 Jan;
42(10):3326-36.
PMID: 23299879
This report presents the synthesis of the first neutral trianionic ONO pincer-type tungsten alkylidyne complex, [CF(3)-ONO]W≡C((t)Bu)(OEt(2)) (5) {where CF(3)-ONO = (MeC(6)H(3)[C(CF(3))(2)O])(2)N(3-)}. Treating 5 with 1-phenylpropyne, 4,4-dimethyl-2-pentyne, and cyclooctyne yields the...