Lubomir Pospisil
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Explore the profile of Lubomir Pospisil including associated specialties, affiliations and a list of published articles.
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Recent Articles
1.
Urbanova V, Bartl T, Vavrek F, Paces O, Pospisil L, Michl J
Langmuir
. 2024 Jan;
40(5):2562-2566.
PMID: 38276954
An electrochemical Langmuir-Blodgett trough that permits an examination of local redox processes in a layer floating on the surface of water with a scanning tunneling microscopy-tip ultramicroelectrode has been constructed...
2.
Janousek J, Rybacek J, Budesinsky M, Pospisil L, Stara I, Stary I
Molecules
. 2022 Nov;
27(21).
PMID: 36364465
The synthesis of a tetrathiafulvalene (TTF) derivative, -[4-({4-[(2,2'-bi-1,3-dithiol-4-ylmethoxy)methyl] phenyl}ethynyl)phenyl] ethanethioate, suitable for the modification of gold nanoparticles (AuNPs), is described in this article. The TTF ligand was self-assembled on the...
3.
Gosset A, Novakova Lachmanova S, Cherraben S, Bertho G, Forte J, Perruchot C, et al.
Chemistry
. 2021 Nov;
27(71):17889-17899.
PMID: 34761431
The synergistic functioning of redox-active components that emerges from prototypical 2,2'-di(N-methylpyrid-4-ylium)-1,1'-biphenyl is described. Interestingly, even if a trans conformation of the native assembly is expected, due to electrostatic repulsion between...
4.
Reyes-Gutierrez P, Amatov T, Svec P, Cisarova I, Saman D, Pohl R, et al.
Chempluschem
. 2020 May;
85(10):2212-2218.
PMID: 32400944
Helquats (HQs) are structurally linked to helicenes and viologens, and they represent an attractive field of research in chemistry and medicinal chemistry. In the present work they were used as...
5.
Gosset A, Wilbraham L, Novakova Lachmanova S, Sokolova R, Dupeyre G, Tuyeras F, et al.
J Am Chem Soc
. 2020 Feb;
142(11):5162-5176.
PMID: 32101420
Molecular-level multielectron handling toward electrical storage is a worthwhile approach to solar energy harvesting. Here, a strategy which uses chemical bonds as electron reservoirs is introduced to demonstrate the new...
6.
Miller J, Cook A, Simkova L, Pospisil L, Ludvik J, Michl J
J Phys Chem B
. 2019 Oct;
123(45):9668-9676.
PMID: 31626548
A massive structural change accompanies electron capture by the 1,2-dicarba--dodecaborane cage molecule (). Bimolecular electron transfer (ET) by pulse radiolysis found a reduction potential of = -1.92 V vs Fc...
7.
Kaiser R, Necas D, Cadart T, Gyepes R, Cisarova I, Mosinger J, et al.
Angew Chem Int Ed Engl
. 2019 Sep;
58(48):17169-17174.
PMID: 31539185
This work presents a general approach for synthesis of substituted [5]-helical dispiroindeno[2,1-c]fluorenes based on Rh-catalyzed intramolecular cyclotrimerization of triynes. This approach was further extended for the first synthesis of configurationally...
8.
Tarabek J, Wen J, Dron P, Pospisil L, Michl J
J Org Chem
. 2018 Apr;
83(10):5474-5479.
PMID: 29652151
We report the electron paramagnetic resonance spectra of the radical cation and radical anion of 1,2,2,3-tetramethyl-2,3-dihydro-1 H-naphtho[2,3- d]imidazole-4,9-dione (1) and its doubly C labeled analogue 2, of interest for singlet...
9.
Brandt J, Pospisil L, Bednarova L, da Costa R, White A, Mori T, et al.
Chem Commun (Camb)
. 2017 Jul;
53(65):9059-9062.
PMID: 28737778
Electrochemical reduction of an azoniahelicene affords a dimer, accompanied by a strong change in the electronic circular dichroism. The fast dimerisation event leads to a >500 mV shift of the...
10.
Buckley L, Coe B, Rusanova D, Sanchez S, Jirasek M, Joshi V, et al.
Dalton Trans
. 2017 Jan;
46(4):1052-1064.
PMID: 28050611
Three new dipolar cations have been synthesised, containing ferrocenyl (Fc) electron donor groups attached to helquat (Hq) acceptors. These organometallic Hq derivatives have been characterised as their TfO salts by...