Julius Rebek Jr
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Explore the profile of Julius Rebek Jr including associated specialties, affiliations and a list of published articles.
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Articles
225
Citations
1922
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Recent Articles
1.
Zhu Y, Gao Y, Rebek J, Rebek Jr J, Yu Y
Chemistry
. 2025 Jan;
31(15):e202404424.
PMID: 39744860
Pillararenes and their derivatives have emerged in supramolecular chemistry as unique macrocycles for applications in host-guest chemistry, materials science and biomimetics. Many variations have been conceived and synthesized in recent...
2.
Zhu Y, Gao Y, Liu W, Rebek Jr J, Yu Y
Chem Commun (Camb)
. 2024 Dec;
61(7):1275-1281.
PMID: 39688274
Macrocyclic structures are popular in supramolecular chemistry and have enjoyed considerable success as platforms for elaboration to container compounds and new materials. Host/guest studies in organic media have relied heavily...
3.
Norjmaa G, Rebek Jr J, Himo F
Chemistry
. 2024 Jan;
30(13):e202303911.
PMID: 38224206
Methylation of amines inside an introverted resorcinarene-based deep methyl ester cavitand is investigated by means of molecular dynamics simulations and quantum chemical calculations. Experimentally, the cavitand has been shown to...
4.
Kanagaraj K, Rebek Jr J, Yu Y
Chem Commun (Camb)
. 2023 Jun;
59(59):9056-9065.
PMID: 37377149
In the confined space of supramolecular systems, the substrate can be forced into a reactive conformation and labile intermediates may be stabilized while isolated from the bulk solution. In this...
5.
Kanagaraj K, Wang R, Zhao M, Ballester P, Rebek Jr J, Yu Y
J Am Chem Soc
. 2023 Mar;
145(10):5816-5823.
PMID: 36857099
A series of straight-chain (C7-C13) alkyl--methyl aldoximes (R-C(H)═NOMe) were synthesized with various functional groups at the remote ends (alkenes, halogen, -COOH, and NH). Their isomers about the C═N bond showed...
6.
Zhu Y, Zhao M, Rebek Jr J, Yu Y
ChemistryOpen
. 2022 Jun;
11(6):e202200026.
PMID: 35701378
We review here the use of container molecules known as cavitands for performing organic reactions in water. Central to these endeavors are binding forces found in water, and among the...
7.
Tang M, Kanagaraj K, Rebek Jr J, Yu Y
Chem Asian J
. 2022 Jun;
17(15):e202200466.
PMID: 35644928
Groups on the upper rim of cavitands can play major roles in the recognition of small molecules. Water-soluble deep cavitands 1, 2 or 3 bearing the walls upper rim of...
8.
Rahman F, Wang R, Zhang H, Brea O, Himo F, Rebek Jr J, et al.
Angew Chem Int Ed Engl
. 2022 Apr;
61(29):e202205534.
PMID: 35488890
A water-soluble cavitand bearing a benzotriazole upper rim was prepared and characterized. It exists as a dimeric velcraplex in D O, but forms host-guest complexes with hydrophobic and amphiphilic guests....
9.
Wang R, Rebek Jr J, Yu Y
Chem Commun (Camb)
. 2022 Jan;
58(12):1828-1833.
PMID: 35084001
Radical chemistry and host-guest chemistry have each developed rapidly over the past decades and their intersection offers an attractive opportunity for modern applications. Radicals can be introduced into the frameworks...
10.
Yang J, Chen Y, Yu Y, Ballester P, Rebek Jr J
J Am Chem Soc
. 2021 Nov;
143(46):19517-19524.
PMID: 34762414
We report the synthesis and characterization of two water-soluble container compounds (cavitand hosts) with rigidified open ends. One cavitand uses four (CH)'s as spacers to bridge the adjacent walls, while...