John J Kiernicki
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Explore the profile of John J Kiernicki including associated specialties, affiliations and a list of published articles.
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26
Citations
174
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Recent Articles
1.
Dunaway L, Davis A, Carter V, Korir A, Zeller M, Kiernicki J
Organometallics
. 2025 Jan;
44(1):46-53.
PMID: 39822184
Zinc benzoates may provide an element of tunability that is not available to their ubiquitous acetate analogues. Unfortunately, the synthesis, speciation, and coordination chemistry of zinc benzoates are less developed...
2.
Norwine E, Kiernicki J, Zeller M, Szymczak N
Inorg Chem
. 2024 Sep;
63(40):18519-18523.
PMID: 39287153
Within metal/ligand cooperative systems employing acidic groups, studies that empirically assess distance relationships are needed to maximize cooperative interactions with substrates. We report the formation of two Cu(I)-NH complexes using...
3.
Galley S, Higgins R, Kiernicki J, Lopez L, Walensky J, Schelter E, et al.
Inorg Chem
. 2023 Sep;
62(39):15819-15823.
PMID: 37713645
A family of thorium complexes featuring the redox-noninnocent pyridinediimine ligand PDI was synthesized, including (PDI)ThCl (), (PDI)ThCl(THF) (), (PDI)ThCl(THF) () and [(PDI)Th(THF)] () Full characterization of these species shows that...
4.
Beagan D, Kiernicki J, Zeller M, Szymczak N
Angew Chem Int Ed Engl
. 2023 Jan;
62(13):e202218907.
PMID: 36720708
We present a ligand platform featuring appended ditopic Lewis acids to facilitate capture/activation of diatomic substrates. We show that incorporation of two 9-borabicyclo[3.3.1]nonane (9-BBN) units on a single carbon tethered...
5.
Norwine E, Kiernicki J, Zeller M, Szymczak N
J Am Chem Soc
. 2022 Aug;
144(33):15038-15046.
PMID: 35960993
We disclose a 1,4,7-triazacyclononane (TACN) ligand featuring an appended boron Lewis acid. Metalation with Cu(I) affords a series of tetrahedral complexes including a boron-capped cuprous hydride. We demonstrate distinct reactivity...
6.
Nasrallah D, Zehnder T, Ludwig J, Steigerwald D, Kiernicki J, Szymczak N, et al.
Angew Chem Int Ed Engl
. 2022 Mar;
61(22):e202112101.
PMID: 35275430
We describe the development of an efficient method for the olefination of hydrazones and oximes. The key design approach that enables this transformation is tuning of the energy/polarity of C=N...
7.
Kiernicki J, Norwine E, Zeller M, Szymczak N
Inorg Chem
. 2021 Jul;
60(18):13806-13810.
PMID: 34242009
Metal-ligand cooperative binding modes were interrogated in a series of zinc bis(thiophenoxide) complexes. A weak B-S binding interaction is observed in solution between the weakly Lewis basic thiophenoxide ligands and...
8.
Kiernicki J, Norwine E, Lovasz M, Zeller M, Szymczak N
Chem Commun (Camb)
. 2020 Oct;
56(86):13105-13108.
PMID: 33016291
Distance dependence of appended Lewis acids in NH binding and deprotonation was evaluated within a series of zinc complexes. Variation of spacer-length to a tethered trialkylborane Lewis acid revealed distinct...
9.
Kiernicki J, Zeller M, Szymczak N
Inorg Chem
. 2020 Jun;
59(13):9279-9286.
PMID: 32551605
We outline the generality and requirements for cooperative NH capture, N-N bond scission, and amido stabilization across a series of first-row transition metal complexes bearing a pyridine(dipyrazole) ligand. This ligand...
10.
Kiernicki J, Norwine E, Zeller M, Szymczak N
Chem Commun (Camb)
. 2019 Sep;
55(79):11896-11899.
PMID: 31528878
We present the preparation of a nitrogen-based bidentate ligand featuring an appended boron Lewis acid as well as its tetrahedral Fe2+ and Zn2+ complexes. These complexes act as platforms for...