Jiaxiang Chu
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Explore the profile of Jiaxiang Chu including associated specialties, affiliations and a list of published articles.
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17
Citations
84
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Recent Articles
1.
Yang J, Zhang C, Chu J
IUCrdata
. 2024 Jul;
9(Pt 6):x240497.
PMID: 38974852
In the title compound, [Mn(CHNO)(CHN)]·2CHCl, the central Mn ion is coordinated by four pyrrole N atoms of the porphyrin core in the basal sites and one N atom of the...
2.
Yang J, Zhang C, Chu J
IUCrdata
. 2024 Jul;
9(Pt 6):x240496.
PMID: 38974845
The title compound, [Fe(CHNO)Cl], crystallizes in space group 2. The central Fe cation (site symmetry 2) is coordinated in a fivefold manner, with four pyrrole N atoms of the porphyrin...
3.
Zhang C, Dankert F, Jiang Z, Wang B, Munz D, Chu J
Angew Chem Int Ed Engl
. 2023 Jun;
62(34):e202307352.
PMID: 37319123
The C-C bond formation between C1 molecules plays an important role in chemistry as manifested by the Fischer-Tropsch (FT) process. Serving as models for the FT process, we report here...
4.
Wang B, Seo C, Zhang C, Chu J, Szymczak N
J Am Chem Soc
. 2022 Aug;
144(34):15793-15802.
PMID: 35973127
Two borane-functionalized bidentate phosphine ligands that vary in tether length have been prepared to examine cooperative metal-substrate interactions. Ni(0) complexes react with aryl azides at low temperatures to form structurally...
5.
Wong A, Chu J, Wu G, Telser J, Dobrovetsky R, Menard G
Inorg Chem
. 2020 Jul;
59(14):10343-10352.
PMID: 32643930
We report the synthesis of new Lewis-acidic boranes tethered to redox-active vanadium centers, (PhN)V(μ-N)B(CF) () and (N(CHCHN(CF)))V(μ-N)B(CF) (). Redox control of the V couple resulted in switchable borane versus "hidden"...
6.
Kurogi T, Chu J, Chen Y, Mindiola D
Chem Asian J
. 2019 Jun;
14(15):2629-2638.
PMID: 31233290
A sterically encumbering multidentate β-diketiminato ligand, L2 ( L2=[ArNC(tBu)CHC(tBu)NCH CH N(Me)CH CH NMe ] , Ar=2,6-iPr C H ), is reported in this study along with its coordination chemistry to...
7.
Chu J, Carroll T, Wu G, Telser J, Dobrovetsky R, Menard G
J Am Chem Soc
. 2018 Nov;
140(45):15375-15383.
PMID: 30382703
Recent computational studies suggest that the phosphate support in the commercial vanadium phosphate oxide (VPO) catalyst may play a critical role in initiating butane C-H bond activation through a mechanism...
8.
Lu E, Chu J, Chen Y
Acc Chem Res
. 2018 Jan;
51(2):557-566.
PMID: 29381048
Research into transition metal complexes bearing multiply bonded main-group ligands has developed into a thriving and fruitful field over the past half century. These complexes, featuring terminal M═E/M≡E (M =...
9.
Munz D, Chu J, Melaimi M, Bertrand G
Angew Chem Int Ed Engl
. 2016 Sep;
55(41):12886-90.
PMID: 27628756
The synthesis of N-heterocyclic carbene (NHC)-cyclic (alkyl)(amino) carbene (CAAC) heterodimers is presented. As the free carbenes do not react together in solution, the synthetic approach involves the addition of a...
10.
Chu J, Munz D, Jazzar R, Melaimi M, Bertrand G
J Am Chem Soc
. 2016 Jun;
138(25):7884-7.
PMID: 27304485
A versatile methodology, involving readily available starting materials, allows for the synthesis of stable hemilabile bidentate cyclic (alkyl)(amino)carbenes (CAACs) featuring alkene, ether, amine, imine, and phosphine functionalities. The stability of...