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Jeffrey R Long

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Articles 318
Citations 6601
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Recent Articles
11.
Lussier D, Ito E, McClain K, Smith P, Kwon H, Rutkauskaite R, et al.
J Am Chem Soc . 2024 Jul; 146(31):21280-21295. PMID: 39044394
The actinide elements are attractive alternatives to transition metals or lanthanides for the design of exchange-coupled multinuclear single-molecule magnets. However, the synthesis of such compounds is challenging, as is unraveling...
12.
Kwon H, McClain K, Kragskow J, Staab J, Ozerov M, Meihaus K, et al.
J Am Chem Soc . 2024 Jun; 146(27):18714-18721. PMID: 38924484
Mixed-valence dilanthanide complexes of the type (Cp)LnI (Cp = pentaisopropylcyclopentadienyl; Ln = Gd, Tb, Dy) featuring a direct Ln-Ln σ-bonding interaction have been shown to exhibit well-isolated high-spin ground states...
13.
Peng P, Jiang H, Collins S, Furukawa H, Long J, Breunig H
ACS Energy Lett . 2024 Jun; 9(6):2727-2735. PMID: 38903404
Materials-based H storage plays a critical role in facilitating H as a low-carbon energy carrier, but there remains limited guidance on the technical performance necessary for specific applications. Metal-organic framework...
14.
Wang H, Su G, Barnett B, Drisdell W, Long J, Prendergast D
Phys Chem Chem Phys . 2024 Apr; 26(15):11980-11987. PMID: 38573245
The L-edge X-ray absorption spectra of late transition metals such as Cu, Ag, and Au exhibit absorption onsets lower in energy for higher oxidation states, which is at odds with...
15.
Zhu Z, Tsai H, Parker S, Lee J, Yabuuchi Y, Jiang H, et al.
J Am Chem Soc . 2024 Feb; 146(9):6072-6083. PMID: 38400985
Diamine-appended Mg(dobpdc) (dobpdc = 4,4'-dioxidobiphenyl-3,3'-dicarboxylate) metal-organic frameworks are promising candidates for carbon capture that exhibit exceptional selectivities and high capacities for CO. To date, CO uptake in these materials has...
16.
Chakraborty R, Talbot J, Shen H, Yabuuchi Y, Carsch K, Jiang H, et al.
Phys Chem Chem Phys . 2024 Feb; 26(8):6490-6511. PMID: 38324335
A detailed chemical understanding of H interactions with binding sites in the nanoporous crystalline structure of metal-organic frameworks (MOFs) can lay a sound basis for the design of new sorbent...
17.
Carsch K, Huang A, Dods M, Parker S, Rohde R, Jiang H, et al.
J Am Chem Soc . 2024 Jan; 146(5):3160-3170. PMID: 38276891
High or enriched-purity O is used in numerous industries and is predominantly produced from the cryogenic distillation of air, an extremely capital- and energy-intensive process. There is significant interest in...
18.
Hou K, Borgel J, Jiang H, SantaLucia D, Kwon H, Zhuang H, et al.
Science . 2023 Nov; 382(6670):547-553. PMID: 37917685
In nature, nonheme iron enzymes use dioxygen to generate high-spin iron(IV)=O species for a variety of oxygenation reactions. Although synthetic chemists have long sought to mimic this reactivity, the enzyme-like...
19.
Babaei H, Meihaus K, Long J
Chem Mater . 2023 Aug; 35(16):6220-6226. PMID: 37637009
The ability to control thermal transport is critical for the design of thermal rectifiers, logic gates, and transistors, although it remains a challenge to design materials that exhibit large changes...
20.
Zhu Z, Parker S, Forse A, Lee J, Siegelman R, Milner P, et al.
J Am Chem Soc . 2023 Jul; 145(31):17151-17163. PMID: 37493594
Diamine-appended Mg(dobpdc) (dobpdc = 4,4'-dioxidobiphenyl-3,3'-dicarboxylate) metal-organic frameworks have emerged as promising candidates for carbon capture owing to their exceptional CO selectivities, high separation capacities, and step-shaped adsorption profiles, which arise...