James Eills
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Explore the profile of James Eills including associated specialties, affiliations and a list of published articles.
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Articles
28
Citations
352
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Recent Articles
1.
Van Dyke E, Eills J, Sheberstov K, Blanchard J, Wagner M, Wedenig A, et al.
Phys Chem Chem Phys
. 2025 Mar;
PMID: 40042078
Fundamental weak interactions have been shown to violate parity in both nuclear and atomic systems. However, observation of parity violation in a molecular system has proven an elusive target. Nuclear...
2.
Mangas-Florencio L, Herrero-Gomez A, Eills J, Azagra M, Batllo-Rius M, Marco-Rius I
Anal Chem
. 2025 Jan;
97(3):1594-1602.
PMID: 39813686
Nuclear magnetic resonance (NMR) spectroscopy is a valuable diagnostic tool limited by low sensitivity due to low nuclear spin polarization. Hyperpolarization techniques, such as dissolution dynamic nuclear polarization, significantly enhance...
3.
Eills J, Mitchell M, Rius I, Tayler M
Proc Natl Acad Sci U S A
. 2024 Oct;
121(43):e2410209121.
PMID: 39405351
Hyperpolarized nuclear spins in molecules exhibit high magnetization that is unachievable by classical polarization techniques, making them widely used as sensors in physics, chemistry, and medicine. The state of a...
4.
Dagys L, Korzeczek M, Parker A, Eills J, Blanchard J, Bengs C, et al.
Sci Adv
. 2024 Jul;
10(30):eado0373.
PMID: 39047103
Parahydrogen-induced polarization (PHIP) is a potent technique for generating target molecules with high nuclear spin polarization. The PHIP process involves a chemical reaction between parahydrogen and a target molecule, followed...
5.
Gierse M, Dagys L, Keim M, Lucas S, Josten F, Plenio M, et al.
Angew Chem Int Ed Engl
. 2024 May;
63(34):e202319341.
PMID: 38805673
Parahydrogen-induced polarization (PHIP) is an inexpensive way to produce hyperpolarized molecules with polarization levels of >10 % in the solution-state, but is strongly limited in generality since it requires chemical...
6.
Wen Y, Fernandez-Sabate M, Lledos A, Sciortino G, Eills J, Marco-Rius I, et al.
Angew Chem Int Ed Engl
. 2024 Apr;
63(26):e202404955.
PMID: 38639173
A combined computational and experimental approach allowed us to develop overall the most selective catalyst for the direct hydrogenation of N-methyl, N-alkyl and N-aryl imines described to date. Iridium catalysts...
7.
Eills J, Picazo-Frutos R, Bondar O, Cavallari E, Carrera C, Barker S, et al.
Anal Chem
. 2023 Dec;
95(49):17997-18005.
PMID: 38047582
We demonstrate that enzyme-catalyzed reactions can be observed in zero- and low-field NMR experiments by combining recent advances in parahydrogen-based hyperpolarization methods with state-of-the-art magnetometry. Specifically, we investigated two model...
8.
Dagys L, Ripka B, Leutzsch M, Moustafa G, Eills J, Colell J, et al.
Magn Reson (Gott)
. 2023 Oct;
1(2):175-186.
PMID: 37904826
In the majority of hydrogenative parahydrogen-induced polarization (PHIP) experiments, the hydrogen molecule undergoes pairwise addition to an unsaturated precursor to occupy vicinal positions on the product molecule. However, some ruthenium-based...
9.
Chuchkova L, Bodenstedt S, Picazo-Frutos R, Eills J, Tretiak O, Hu Y, et al.
J Phys Chem Lett
. 2023 Jul;
14(30):6814-6822.
PMID: 37486855
Photochemically induced dynamic nuclear polarization (photo-CIDNP) enables nuclear spin ordering by irradiating samples with light. Polarized spins are conventionally detected via high-field chemical-shift-resolved NMR (above 0.1 T). In this Letter,...
10.
Eills J, Picazo-Frutos R, Burueva D, Kovtunova L, Azagra M, Marco-Rius I, et al.
Chem Commun (Camb)
. 2023 Jul;
59(62):9509-9512.
PMID: 37450281
We show that catalyst-free aqueous solutions of hyperpolarized [1-C]succinate can be produced using parahydrogen-induced polarization (PHIP) and a combination of homogeneous and heterogeneous catalytic hydrogenation reactions. We generate hyperpolarized [1-C]fumarate...