Jacob R Lindale
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Explore the profile of Jacob R Lindale including associated specialties, affiliations and a list of published articles.
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Articles
14
Citations
144
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Recent Articles
1.
Lindale J, Warren W
Sci Adv
. 2025 Feb;
11(8):eadq9974.
PMID: 39970215
Coherent evolution is punctuated by dynamical processes such as chemical exchange, conformational transformation, or site hopping in many important problems ranging from biomolecular function to ion trap quantum computation. One...
2.
Lindale J, Smith L, Mammen M, Eriksson S, Everhart L, Warren W
Proc Natl Acad Sci U S A
. 2024 Mar;
121(14):e2400066121.
PMID: 38536754
The inherently low signal-to-noise ratio of NMR and MRI is now being addressed by hyperpolarization methods. For example, iridium-based catalysts that reversibly bind both parahydrogen and ligands in solution can...
3.
Eriksson S, Mammen M, Eriksson C, Lindale J, Warren W
J Magn Reson
. 2022 Aug;
342:107282.
PMID: 35970048
Signal Amplification By Reversible Exchange (SABRE) and the heteronuclear variant, X-SABRE, increase the sensitivity of magnetic resonance techniques using order derived from reversible binding of para-hydrogen. One current limitation of...
4.
Li X, Lindale J, Eriksson S, Warren W
Phys Chem Chem Phys
. 2022 May;
24(27):16462-16470.
PMID: 35552575
SABRE (Signal Amplification by Reversible Exchange) methods provide a simple, fast, and cost-effective method to hyperpolarize a wide variety of molecules in solution, and have been demonstrated with protons and,...
5.
Eriksson S, Lindale J, Li X, Warren W
Sci Adv
. 2022 Mar;
8(11):eabl3708.
PMID: 35294248
Signal amplification by reversible exchange (SABRE) creates "hyperpolarization" (large spin magnetization) using a transition metal catalyst and parahydrogen, addressing the sensitivity limitations of magnetic resonance. SABRE and its heteronuclear variant...
6.
Lindale J, Eriksson S, Warren W
Phys Chem Chem Phys
. 2022 Mar;
24(12):7214-7223.
PMID: 35266466
Hyperpolarization methods in magnetic resonance overcome sensitivity limitations, especially for low-γ nuclei such as C and N. Signal Amplification By Reversible Exchange (SABRE) and extended SABRE (X-SABRE) are efficient and...
7.
Lindale J, Eriksson S, Tanner C, Warren W
Sci Adv
. 2020 Aug;
6(32):eabb6874.
PMID: 32821841
Many important applications in biochemistry, materials science, and catalysis sit squarely at the interface between quantum and statistical mechanics: Coherent evolution is interrupted by discrete events, such as binding of...
8.
Colell J, Logan A, Zhou Z, Lindale J, Laasner R, Shchepin R, et al.
Chem Commun (Camb)
. 2020 Jul;
56(65):9336-9339.
PMID: 32671356
Here we report on chelating ligands for Signal Amplification By Reversible Exchange (SABRE) catalysts that permit hyperpolarisation on otherwise sterically hindered substrates. We demonstrate H enhancements of ∼100-fold over 8.5...
9.
Gemeinhardt M, Limbach M, Gebhardt T, Eriksson C, Eriksson S, Lindale J, et al.
Angew Chem Int Ed Engl
. 2019 Oct;
59(1):418-423.
PMID: 31661580
Herein, we demonstrate "direct" C hyperpolarization of C-acetate via signal amplification by reversible exchange (SABRE). The standard SABRE homogeneous catalyst [Ir-IMes; [IrCl(COD)(IMes)], (IMes=1,3-bis(2,4,6-trimethylphenyl), imidazole-2-ylidene; COD=cyclooctadiene)] was first activated in the...
10.
Lindale J, Tanner C, Eriksson S, Warren W
J Magn Reson
. 2019 Aug;
307:106577.
PMID: 31454701
Signal Amplification By Reversible Exchange, or SABRE, uses the singlet-order of parahydrogen to generate hyperpolarized signals on target nuclei, bypassing the limitations of traditional magnetic resonance. Experiments performed directly in...