J Terence Blaskovits
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Explore the profile of J Terence Blaskovits including associated specialties, affiliations and a list of published articles.
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15
Citations
117
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Recent Articles
1.
Blaskovits J, Corminboeuf C, Garner M
J Phys Chem A
. 2024 Nov;
128(48):10404-10412.
PMID: 39568342
Molecules with Hund's rule violations between low-lying singlet and triplet states may enable a new generation of fluorescent emitters. However, only a few classes of molecules are known with this...
2.
Blaskovits J, Corminboeuf C, Garner M
J Phys Chem Lett
. 2024 Sep;
15(40):10062-10067.
PMID: 39325862
Molecules where the lowest excited singlet state is lower in energy than the lowest triplet are highly promising for a number of organic materials applications as efficiency limitations stemming from...
3.
Schaufelberger L, Blaskovits J, Laplaza R, Jorner K, Corminboeuf C
Angew Chem Int Ed Engl
. 2024 Sep;
64(3):e202415056.
PMID: 39321389
Singlet fission has shown potential for boosting the efficiency of solar cells, but the scarcity of suitable molecular materials hinders its implementation. We introduce an uncertainty-controlled genetic algorithm (ucGA) based...
4.
Das S, Laplaza R, Blaskovits J, Corminboeuf C
J Am Chem Soc
. 2024 May;
146(23):15806-15814.
PMID: 38814248
Frustrated Lewis pairs (FLPs), featuring reactive combinations of Lewis acids and Lewis bases, have been utilized for myriad metal-free homogeneous catalytic processes. Immobilizing the active Lewis sites to a solid...
5.
Garner M, Blaskovits J, Corminboeuf C
Chem Commun (Camb)
. 2024 Jan;
60(15):2070-2073.
PMID: 38291965
Inverted singlet-triplet gaps may lead to novel molecular emitters if a rational design approach can be achieved. We uncover a substituent strategy that enables tuning of the gap and succeed...
6.
Blaskovits J, Laplaza R, Vela S, Corminboeuf C
Adv Mater
. 2023 Oct;
36(2):e2305602.
PMID: 37815223
The high-throughput exploration and screening of molecules for organic electronics involves either a 'top-down' curation and mining of existing repositories, or a 'bottom-up' assembly of user-defined fragments based on known...
7.
Garner M, Blaskovits J, Corminboeuf C
Chem Sci
. 2023 Oct;
14(38):10458-10466.
PMID: 37800005
Molecules where the first excited singlet state is lower in energy than the first excited triplet state have the potential to revolutionize OLEDs. This inverted singlet-triplet gap violates Hund's rule...
8.
Blaskovits J, Garner M, Corminboeuf C
Angew Chem Int Ed Engl
. 2023 Feb;
62(15):e202218156.
PMID: 36786076
Molecules with inversion of the singlet and triplet excited-state energies are highly promising for the development of organic light-emitting diodes (OLEDs). To date, azaphenalenes are the only class of molecules...
9.
Das S, Laplaza R, Blaskovits J, Corminboeuf C
Angew Chem Int Ed Engl
. 2022 Apr;
61(32):e202202727.
PMID: 35447004
The immobilization of molecular catalysts imposes spatial constraints on their active site. We reveal that in bifunctional catalysis such constraints can also be utilized as an appealing handle to boost...
10.
Blaskovits J, Fumanal M, Vela S, Cho Y, Corminboeuf C
Chem Commun (Camb)
. 2022 Jan;
58(9):1338-1341.
PMID: 34985471
Singlet fission (SF) is a promising multiexciton-generating process. Its demanding energy splitting criterion - that the S energy must be at least twice that of T - has limited the...