Iskander Douair
Overview
Explore the profile of Iskander Douair including associated specialties, affiliations and a list of published articles.
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Articles
38
Citations
269
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Recent Articles
1.
Pedussaut L, Mahieu N, Chartier C, Rajeshkumar T, Tricoire M, Douair I, et al.
Chem Sci
. 2024 Nov;
15(46):19273-19282.
PMID: 39568911
The cyclononatetraenyl (Cnt) ligand is a large monoanionic ligand. It is easily synthesized by ring expansion after cyclopropanation of the cyclooctatetraenyl (Cot) ligand. The Cnt ligand can be reported as...
2.
Brackbill I, Rajeshkumar T, Douair I, Maron L, Boreen M, Bergman R, et al.
J Am Chem Soc
. 2024 Jul;
146(31):21932-21947.
PMID: 39051942
The electronic organization of Frustrated Lewis Pairs (FLPs) allows them to activate strong bonds in mechanisms that are usually free of redox events at the Lewis acidic site. The unique...
3.
Controlling Extraction of Rare Earth Elements Using Functionalized Aryl-vinyl Phosphonic Acid Esters
Kuvayskaya A, Mallos T, Douair I, Chang C, Larsen R, Jensen M, et al.
Inorg Chem
. 2023 Sep;
62(40):16343-16353.
PMID: 37751598
Ligands that can discriminate between individual rare earth elements are important for production of these critical elements. A set of aryl-vinyl phosphonic acid ligands for extracting rare earth elements were...
4.
Ruoff K, Gish M, Song E, Douair I, Pandey P, Steger M, et al.
J Am Chem Soc
. 2023 Jul;
145(30):16374-16382.
PMID: 37467432
Manifesting chemical differences in individual rare earth (RE) element complexes is challenging due to the similar sizes of the tripositive cations and the corelike 4f shell. We disclose a new...
5.
Theodosopoulou D, De La Pena M, Abou Derhamine S, Douair I, Roisnel T, Cordier M, et al.
Dalton Trans
. 2023 Jun;
52(25):8620-8630.
PMID: 37284797
A series of new MeSi-bridged cyclopentadiene/indene proligands {MeSi(R-R-Cp)(R,R,R,R-Ind)H} (1a-j) with various substitutions both on the indene and cyclopentadiene moieties was prepared. The corresponding -symmetric group 4 -metallocene complexes (M =...
6.
Yuvaraj K, Mullins J, Rajeshkumar T, Douair I, Maron L, Jones C
Chem Sci
. 2023 May;
14(19):5188-5195.
PMID: 37206401
Reactions of a dimagnesium(i) compound, [{(Nacnac)Mg}] (Nacnac = [HC(MeCNDip)], Dip = 2,6-diisopropylphenyl), pre-activated by coordination with simple Lewis bases (4-dimethylaminopyridine, DMAP; or TMC, :C(MeNCMe)), with 1 atmosphere of CO in...
7.
Xin X, Douair I, Zhao Y, Wang S, Maron L, Zhu C
Natl Sci Rev
. 2023 Mar;
10(2):nwac144.
PMID: 36950222
The Haber-Bosch process produces ammonia (NH) from dinitrogen (N) and dihydrogen (H), but requires high temperature and pressure. Before iron-based catalysts were exploited in the current industrial Haber-Bosch process, uranium-based...
8.
Xin X, Douair I, Rajeshkumar T, Zhao Y, Wang S, Maron L, et al.
Nat Commun
. 2022 Jul;
13(1):3809.
PMID: 35778419
Uranium nitrides play important roles in dinitrogen activation and functionalization and in chemistry for nuclear fuels, but the synthesis and isolation of the highly reactive uranium(VI) nitrides remains challenging. Here,...
9.
Garg P, Carpentier A, Douair I, Dange D, Jiang Y, Yuvaraj K, et al.
Angew Chem Int Ed Engl
. 2022 Mar;
61(20):e202201705.
PMID: 35238149
Reaction of the 1,2-disilylene, [{ArC(NDip) }Si] 1 (Dip=2,6-diisopropylphenyl, Ar=4-C H Bu ), with CO proceeds via insertion of CO into one Si-N bond, and Si-Si bond cleavage, to cleanly give...
10.
Willauer A, Douair I, Chauvin A, Fadaei-Tirani F, Bunzli J, Maron L, et al.
Chem Sci
. 2022 Feb;
13(3):681-691.
PMID: 35173932
Among the 14 lanthanide elements (Ce-Lu), until recently, the tetravalent oxidation state was readily accessible in solution only for cerium while Pr(iv), Nd(iv), Dy(iv) and Tb(iv) had only been detected...