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Iacopo Ciabatti

Explore the profile of Iacopo Ciabatti including associated specialties, affiliations and a list of published articles. Areas
Snapshot
Articles 22
Citations 51
Followers 0
Related Specialties
Chemistry
Biotechnology
Top 10 Co-Authors
Cristina Femoni
Stefano Zacchini
Maria Carmela Iapalucci
Giuliano Longoni
Mohammad Hayatifar
Marco Bortoluzzi
Cristiana Cesari
Beatrice Berti
Fabrizia Fabrizi de Biani
Tiziana Funaioli
Published In
Inorg Chem
Dalton Trans
Nanoscale
Angew Chem Int Ed Engl
ACS Omega
Affiliations
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Recent Articles
1.
Metal Segregation in Bimetallic CoPd Carbide Carbonyl Clusters: Synthesis, Structure, Reactivity and Electrochemistry of [H Co Pd C (CO) ] (n=3-6)
Ciabatti I, Fabrizi de Biani F, Femoni C, Iapalucci M, Longoni G, Zacchini S
Chempluschem . 2020 Jan; 78(12):1456-1465. PMID: 31986665
Nanometric CoPd bimetallic [H Co Pd C (CO) ] (n=3-6) tetracarbide carbonyl clusters have been prepared by redox condensation of [Co C(CO) ] with [PdCl (Et S) ]. The crystal...
2.
Cluster Core Isomerism Induced by Crystal Packing Effects in the [HCoPdC(CO)] Molecular Nanocluster
Berti B, Ciabatti I, Femoni C, Iapalucci M, Zacchini S
ACS Omega . 2019 Aug; 3(10):13239-13250. PMID: 31458042
This article describes a rare case of cluster core isomerism in a large molecular organometallic nanocluster. In particular, two isomers of the [HCoPdC(CO)] nanocluster, referred as TP-Pd and Oh-Pd, have...
3.
Synthesis of [Pt(CO)(dppm)] and [Pt(CO)(dppm)] Heteroleptic Chini-type Platinum Clusters by the Oxidative Oligomerization of [Pt(CO)(dppm)]
Berti B, Cesari C, Conte F, Ciabatti I, Femoni C, Iapalucci M, et al.
Inorg Chem . 2018 Jun; 57(13):7578-7590. PMID: 29889503
The reactions of [Pt(CO)] with CH(PPh) (dppm), CH═C(PPh) (P^P), and Fe(CHPPh) (dppf) proceed via nonredox substitution and result in the heteroleptic Chini-type clusters [Pt(CO)(dppm)], [Pt(CO)(P^P)], and [Pt(CO)(dppf)], respectively. Conversely, the...
4.
Water soluble derivatives of platinum carbonyl Chini clusters: synthesis, molecular structures and cytotoxicity of [Pt(CO)(PTA)] and [Pt(CO)(PTA)] 
Batchelor L, Berti B, Cesari C, Ciabatti I, Dyson P, Femoni C, et al.
Dalton Trans . 2018 Mar; 47(13):4467-4477. PMID: 29504622
The reactions of [Pt3n(CO)6n]2- (n = 2-5) homoleptic Chini-type clusters with increasing amounts of 1,3,5-triaza-7-phosphaadamantane (PTA) result in the stepwise substitution of one terminal CO ligand per Pt3 triangular unit...
5.
Molecular Nickel Phosphide Carbonyl Nanoclusters: Synthesis, Structure, and Electrochemistry of [NiP(CO)] and [HNiP(CO)] (n = 4 and 5)
Capacci C, Ciabatti I, Femoni C, Iapalucci M, Funaioli T, Zacchini S, et al.
Inorg Chem . 2018 Jan; 57(3):1136-1147. PMID: 29303559
The reaction of [NEt][Ni(CO)] in thf with 0.5 equiv of PCl affords the monophosphide [NiP(CO)] that in turn further reacts with PCl resulting in the tetra-phosphide carbonyl cluster [HNiP(CO)]. Alternatively,...
6.
Interstitial Bismuth Atoms in Icosahedral Rhodium Cages: Syntheses, Characterizations, and Molecular Structures of the [Bi@Rh(CO)], [(Bi@Rh(CO))Bi], [Bi@Rh(CO)Bi], and [Bi@Rh(CO)Bi] Carbonyl Clusters
Femoni C, Bussoli G, Ciabatti I, Ermini M, Hayatifar M, Iapalucci M, et al.
Inorg Chem . 2017 May; 56(11):6343-6351. PMID: 28520423
The reaction of [Rh(CO)] with BiCl under N and at room temperature results in the formation of the new heterometallic [Bi@Rh(CO)] cluster in high yields. Further controlled addition of BiCl...
7.
Reactions of Platinum Carbonyl Chini Clusters with Ag(NHC)Cl Complexes: Formation of Acid-Base Lewis Adducts and Heteroleptic Clusters
Bortoluzzi M, Cesari C, Ciabatti I, Femoni C, Iapalucci M, Zacchini S
Inorg Chem . 2017 May; 56(11):6532-6544. PMID: 28489358
The reactions of anionic platinum carbonyl Chini clusters [Pt(CO)] [n = 2 (1), 3 (2), 4 (3)] with Ag(IPr)Cl [IPr = CNH(CHPr)] afford the neutral acid-base Lewis adducts [Pt(CO)(AgIPr)] (4)...
8.
Heteroleptic Chini-Type Platinum Clusters: Synthesis and Characterization of Bis-Phospine Derivatives of [Pt(CO)] (n = 2-4)
Cesari C, Ciabatti I, Femoni C, Iapalucci M, Mancini F, Zacchini S
Inorg Chem . 2017 Jan; 56(3):1655-1668. PMID: 28124896
The reactions of [Pt(CO)] (n = 2-4) homoleptic Chini-type clusters with stoichiometric amounts of PhPCHCHPPh (dppe) result in the heteroleptic Chini-type clusters [Pt(CO)(dppe)], [Pt(CO)(dppe)], and [Pt(CO)(dppe)]. Their formation is accompanied...
9.
Syntheses, Structures, and Electrochemistry of the Defective ccp [Pt33(CO)38](2-) and the bcc [Pt40(CO)40](6-) Molecular Nanoclusters
Cattabriga E, Ciabatti I, Femoni C, Funaioli T, Iapalucci M, Zacchini S
Inorg Chem . 2016 Jun; 55(12):6068-79. PMID: 27281686
The molecular [Pt33(CO)38](2-) nanocluster was obtained from the thermal decomposition of Na2[Pt15(CO)30] in methanol. The reaction of [Pt19(CO)22](4-) with acids (1-2 equiv) affords the unstable [Pt19(CO)22](3-) trianion, which evolves with...
10.
Platinum carbonyl clusters stabilized by Sn(II)-based fragments: syntheses and structures of [Pt6(CO)6(SnCl2)2(SnCl3)4](4-), [Pt9(CO)8(SnCl2)3(SnCl3)2(Cl2SnOCOSnCl2)](4-) and [Pt10(CO)14{Cl2Sn(OH)SnCl2}2](2.)
Bortoluzzi M, Ceriotti A, Ciabatti I, Della Pergola R, Femoni C, Iapalucci M, et al.
Dalton Trans . 2016 Jan; 45(12):5001-13. PMID: 26795720
The reaction of [Pt15(CO)30](2-) with increasing amounts of SnCl2 affords [Pt8(CO)10(SnCl2)4](2-) (2), [Pt10(CO)14{Cl2Sn(OH)SnCl2}2](2-) (5), [Pt6(CO)6(SnCl2)2(SnCl3)4](4-) (3), [Pt9(CO)8(SnCl2)3(SnCl3)2(Cl2SnOCOSnCl2)](4-) (4) and [Pt5(CO)5{Cl2Sn(OR)SnCl2}3](3-) (R = H, Me, Et, and (i)Pr) (1-R). 1-R and...