Gerard van Koten
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Explore the profile of Gerard van Koten including associated specialties, affiliations and a list of published articles.
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99
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Recent Articles
1.
Valdes H, German-Acacio J, van Koten G, Morales-Morales D
Dalton Trans
. 2022 Jan;
51(5):1724-1744.
PMID: 34985477
This perspective is to illustrate the synthesis and applications of bimetallic complexes by merging a metallocene and a (cyclopentadienyl/aryl) pincer metal complex. Four possible ways to merge metallocene and pincer-metal...
2.
Canty A, Ariafard A, van Koten G
Chemistry
. 2021 Sep;
27(62):15426-15433.
PMID: 34473849
Density functional theory computation indicates that bridge splitting of [Pt R (μ-SEt )] proceeds by partial dissociation to form R Pt (μ-SEt )Pt R (SEt ), followed by coordination of...
3.
Batema G, Korstanje T, Guillena G, Rodriguez G, Lutz M, van Klink G, et al.
Molecules
. 2021 Apr;
26(7).
PMID: 33810499
Post-modification of a series of NCN-pincer platinum(II) complexes [PtX(NCN-R-4)] (NCN = [CH(CHNMe)-2,6], R = C(O)H, C(O)Me and C(O)Et), X = Cl or Br) at the -position using the McMurry reaction...
4.
Canty A, Ariafard A, van Koten G
Chemistry
. 2020 Jul;
26(67):15629-15635.
PMID: 32696509
Density Functional Theory studies of square-planar Pt pincer structures, (4-Z-NCN)PtCl ([4-Z-NCN] =[4-Z-2,6-(Me NCH ) C H -N,C,N] , Z=H, NO , CF , CO H, CHO, Cl, Br, I, F,...
5.
Segaud N, McMaster J, van Koten G, Albrecht M
Inorg Chem
. 2019 Nov;
58(23):16047-16058.
PMID: 31714752
Copper(II) complexes of type (NHC)CuX (X = OAc, Cl, Br, BF, and NO) bearing monodentate -heterocyclic carbenes (NHCs) were prepared by decarboxylation of imidazolium carboxylates as a new synthetic methodology...
6.
Albrecht M, van Koten G
Angew Chem Int Ed Engl
. 2018 May;
40(20):3750-3781.
PMID: 29712145
Since the first reports in the late 1970s on transition metal complexes containing pincer-type ligands-named after the particular coordination mode of these ligands-these systems have attracted increasing interest owing to...
7.
Hovestad N, Eggeling E, Heidbuchel H, Jastrzebski J, Kragl U, Keim W, et al.
Angew Chem Int Ed Engl
. 2018 May;
38(11):1655-1658.
PMID: 29711001
A codimerization of styrene and ethene can be carried out continuously in a nanofiltration membrane reactor with dendritic Pd complexes such as 1. The selectivity of the reaction is increased...
8.
Batema G, Lutz M, Spek A, van Walree C, van Klink G, van Koten G
Dalton Trans
. 2014 Jul;
43(32):12200-9.
PMID: 25007011
A series of organometallic 4,4'-substituted benzylidene aniline complexes 4-ClPt-3,5-(CH2NMe2)2C6H2CH[double bond, length as m-dash]NC6H4R'-4', abbreviated as PtCl[NCN(CH[double bond, length as m-dash]NC6H4R'-4')-4], with R' = NMe2, Me, H, Cl, CN (, respectively),...
9.
Jastrzebski J, Arink A, Kleijn H, Braam T, Lutz M, Spek A, et al.
J Am Chem Soc
. 2013 Sep;
135(36):13371-8.
PMID: 24001235
Regioselectivity is an important aspect in the design of organic protocols involving Directed ortho-Lithiation (DoL) of arenes, in particular with those arenes containing heteroatom substituents as directing groups. The DoL...
10.
Pijnenburg N, Cabon Y, van Koten G, Klein Gebbink R
Chemistry
. 2013 Feb;
19(15):4858-68.
PMID: 23436343
This paper describes a mechanistic study of the SCS-pincer Pd(II)-catalyzed auto-tandem reaction consisting of the stannylation of cinnamyl chloride with hexamethylditin, followed by an electrophilic allylic substitution of the primary...