George Christou
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Explore the profile of George Christou including associated specialties, affiliations and a list of published articles.
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229
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849
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Recent Articles
1.
Anastassiades A, Alexandropoulos D, Hale A, Christou G, Perlepes S, Tasiopoulos A
Cryst Growth Des
. 2024 Nov;
24(21):9076-9083.
PMID: 39534426
The initial use of 2-(pyridin-2-yl)propane-1,3-diol (pypdH) in Mn cluster chemistry has afforded two new mixed-valence polynuclear Mn clusters, namely, [MnΟ(pypd)(hmp)(OCCMe)] () and [MnΟ(N)(pypd){(py)CO}(OCEt)] () (hmp = deprotonated 2-hydroxymethylpyridine; (py)CO =...
2.
Brown S, Marchi S, Thomas C, Hale A, Lockart M, Bowman M, et al.
J Inorg Biochem
. 2023 Dec;
251:112439.
PMID: 38039560
The reduction of the carcinogen chromate has been proposed to lead to three Cr(III)-containing DNA lesions: binary adducts (Cr(III) and DNA), interstrand crosslinks, and ternary adducts (Cr(III) linking DNA to...
3.
Lee K, Christou G
Inorg Chem
. 2023 Nov;
62(49):20005-20019.
PMID: 37922406
The previous development of a magnetostructural correlation (MSC) for polynuclear Fe/oxo clusters has now been extended to one for polynuclear Mn/oxo clusters. A semiempirical model estimating each pairwise Mn exchange...
4.
Mononuclear Four-Coordinate Bis-Fluoride Bis-NHC Complexes of Chromium(II), Iron(II), and Cobalt(II)
Acosta C, Belov D, Lamur A, Brantley C, Solans-Monfort X, Rue K, et al.
Inorg Chem
. 2023 Oct;
62(44):18108-18115.
PMID: 37876243
The reaction between silylamido complexes of Cr(II), Fe(II), and Co(II) and IMes·2HF salt in the presence of IMes (IMes = 1,3-dimesitylimidazol-2-ylidene) led to isolation of Cr(IMes)F (), Fe(IMes)F (), and...
5.
Yazback M, Liu S, Shatruk M, Christou G, Cheng H
J Phys Chem A
. 2023 Apr;
127(17):3814-3823.
PMID: 37093629
Using first-principles methods and spin models, we investigate the magnetic properties of transition-metal trimers Cr and Cu. We calculate exchange coupling constants and zero-field splitting parameters using density functional theory...
6.
Hale A, Abboud K, Christou G
Inorg Chem
. 2023 Apr;
62(15):6020-6031.
PMID: 37015039
New members of the Mn and Mn torus-like cluster family have been prepared from a hybrid comproportionation-alcoholysis reaction of [MnO(OCR)(HO)] in alcohol in the presence of R'COH with NBuMnO or...
7.
Armenis A, Bakali G, Brantley C, Raptopoulou C, Psycharis V, Cunha-Silva L, et al.
Dalton Trans
. 2022 Nov;
51(47):18077-18089.
PMID: 36373936
The systematic investigation of the general reaction scheme Dy/X/LH, where X = Cl, CFSO, ClO, MeCO, and LH is the pocket-type ligand 2,6-diacetylpyridine bis(picolinoylhydrazone), resulting from the condensation of 2,6-diacetylpyridine...
8.
Lee K, Aebersold L, Peralta J, Abboud K, Christou G
Inorg Chem
. 2022 Oct;
61(43):17256-17267.
PMID: 36251497
The synthesis and characterization of a high-nuclearity Fe/O/arsinate cluster is reported within the salt [FeO(OH)(OAsMe)(OCH)(HO)](NO) (). The compound was prepared from the reaction of Fe(NO)·9HO, dimethylarsinic acid (MeAsOH), and triethylamine...
9.
Aebersold L, Hale A, Christou G, Peralta J
J Phys Chem A
. 2022 Sep;
126(38):6790-6800.
PMID: 36129336
In this work, we assess the potential of the Green's function approximation to predict isotropic magnetic exchange couplings and to reproduce the standard broken-symmetry energy difference approach for transition metal...
10.
Skachkov D, Liu S, Chen J, Christou G, Hebard A, Zhang X, et al.
J Phys Chem A
. 2022 Aug;
126(32):5265-5272.
PMID: 35939333
We study intramolecular electron transfer in the single-molecule magnetic complex [MnO(OCR) (HO)] for R = -H, -CH, -CHCl, -CH, and -CHF ligands as a mechanism for switching of the molecular...