Frank W Heinemann
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Explore the profile of Frank W Heinemann including associated specialties, affiliations and a list of published articles.
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204
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1047
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Recent Articles
1.
Mondal A, Breitwieser K, Danes S, Grunwald A, Heinemann F, Morgenstern B, et al.
Angew Chem Int Ed Engl
. 2024 Dec;
64(6):e202418738.
PMID: 39714412
We report hitherto elusive side-on η-bonded palladium(0) carbonyl (anthraquinone, benzaldehyde) and arene (benzene, hexafluorobenzene) palladium(0) complexes and present the catalytic hydrodefluorination of hexafluorobenzene by cyclohexene. The comparison with respective cyclohexene,...
2.
Bergen A, Hemmeter D, Barreto J, Maier F, Scheurer A, Heinemann F, et al.
Chemistry
. 2024 Nov;
31(2):e202402827.
PMID: 39581868
We present the preparation and investigation of a fluorine-free surface-active bis-N-heterocyclic carbene (NHC) platinum(II) complex - trans-[Pt(mPEGCIm)Cl] - for interface-enhanced supported ionic liquid phase (SILP) catalysis within a group of...
3.
Gravogl L, Kass D, Pyschny O, Heinemann F, Haumann M, Katz S, et al.
J Am Chem Soc
. 2024 Oct;
146(42):28757-28769.
PMID: 39382653
The diiron(II) complex, [(OCO)Fe(MeCN)] (, MeCN = acetonitrile), supported by the bis-phenolate carbene pincer ligand, 1,3-bis(3,5-di--butyl-2-hydroxyphenyl)benzimidazolin-2-ylidene (OCO), was synthesized and characterized by single-crystal X-ray diffraction, H nuclear magnetic resonance, infrared...
4.
Sila N, Durrmann A, Weber B, Heinemann F, Irrgang T, Kempe R
J Am Chem Soc
. 2024 Sep;
146(39):26877-26883.
PMID: 39308226
Iron is the most abundant transition metal of the Earth's crust, and the understanding of its function in key technologies, such as catalysis, is highly important. We report here on...
5.
Cooperative spin crossover leading to bistable and multi-inert system states in an iron(III) complex
Durrmann A, Horner G, Baabe D, Heinemann F, de Melo M, Weber B
Nat Commun
. 2024 Aug;
15(1):7321.
PMID: 39183211
Cooperativity among spin centres has long been the royal road in spin crossover (SCO) research to impose magnetic bistability in terms of thermal hysteresis. In this work we access magnetic...
6.
Gravogl L, Keilwerth M, Korber E, Heinemann F, Meyer K
Inorg Chem
. 2024 Aug;
63(34):15888-15905.
PMID: 39145894
Reduction of the ferrous precursor [(TIMMN)Fe(Cl)] () (TIMMN = ris-[(3-mesitylidazol-2-ylidene)ethyl]amie) to the low-valent iron(0) complex [(TIMMN)Fe(CO)] () is presented, where the tris(N-heterocyclic carbene) (NHC) ligand framework remains intact, yet the...
7.
Grasruck A, Schall K, Heinemann F, Langer J, Herrera A, Friess S, et al.
Dalton Trans
. 2024 May;
53(20):8642-8656.
PMID: 38695637
The new hydrazine 5-dibenzo[,]azepin-5-amine (2) reacts with P- and Si-electrophiles deprotonation to afford P(III)-, P(V)-, and TMS-hydrazides 3-8 and with carbonyl electrophiles acid-free condensation to the -substituted hydrazones 9-12 that...
8.
Cotic A, Heinemann F, Slep L, Cadranel A
Chemphyschem
. 2024 Apr;
25(14):e202400246.
PMID: 38656666
In MLCT chromophores, internal conversion (IC) in the form of hole reconfiguration pathways (HR) is a major source of dissipation of the absorbed photon energy. Therefore, it is desirable to...
9.
Keilwerth M, Mao W, Malischewski M, Jannuzzi S, Breitwieser K, Heinemann F, et al.
Nat Chem
. 2024 Jan;
16(4):514-520.
PMID: 38291260
Complexes of iron in high oxidation states are captivating research subjects due to their pivotal role as active intermediates in numerous catalytic processes. Structural and spectroscopic studies of well-defined model...
10.
Leinauer L, Parla G, Messelbeger J, Herrera A, Heinemann F, Langer J, et al.
Chem Commun (Camb)
. 2023 Nov;
59(97):14451-14454.
PMID: 37982441
Alkene planar chirality is introduced in the 'privileged' P-alkene phosphoramidite ligand 1. The resulting diastereomeric ligands (p)-5 and (p)-5 form optically pure complexes of Rh(I) and Pd(II), which catalyze conjugate...