Eva Harth
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Explore the profile of Eva Harth including associated specialties, affiliations and a list of published articles.
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37
Citations
279
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Recent Articles
1.
Kim K, Strong J, Sarkar S, Nguyen D, Dau H, Al-Aman D, et al.
Macromolecules
. 2025 Feb;
58(3):1337-1348.
PMID: 39958487
Accessing a facile pathway to prepare polyolefin-polar block copolymers with low dispersity and high control remains a challenge due to the distinct polymerization pathways of the composing blocks. This study...
2.
Rauf H, Liu Y, Arslan M, Solanki S, Deydier E, Poli R, et al.
ACS Catal
. 2024 Sep;
14(17):13136-13147.
PMID: 39263544
Design of catalysts for Ni-catalyzed olefin polymerization predominantly focuses on ligand design rather than the activation process when attempting to achieve a broader scope of polyolefin micro- and macrostructures. Air-stable...
3.
Kim K, Nguyen D, Strong J, Dadashi-Silab S, Sun M, Dau H, et al.
Macromol Rapid Commun
. 2024 Jan;
45(8):e2300675.
PMID: 38163327
Despite their industrial ubiquity, polyolefin-polyacrylate block copolymers are challenging to synthesize due to the distinct polymerization pathways necessary for respective blocks. This study utilizes MILRad, metal-organic insertion light-initiated radical polymerization,...
4.
Nguyen D, Wang S, Grabow L, Harth E
J Am Chem Soc
. 2023 Apr;
145(17):9755-9770.
PMID: 37071817
This work elucidates a long-standing unexplained paradox commonly observed within the polymerization of α-olefin using palladium (Pd)(II)-diimine catalysts, in which isomerization and living polymerization of α-olefins are both observed. With...
5.
Dau H, Jones G, Tsogtgerel E, Nguyen D, Keyes A, Liu Y, et al.
Chem Rev
. 2022 Aug;
122(18):14471-14553.
PMID: 35960550
Block copolymers form the basis of the most ubiquitous materials such as thermoplastic elastomers, bridge interphases in polymer blends, and are fundamental for the development of high-performance materials. The driving...
6.
Lampley M, Harth E
ACS Macro Lett
. 2022 May;
7(6):745-750.
PMID: 35632958
We report the preparation of photoresponsive nanomaterials and the increase of their nanoscopic size through a "photogrowth" mechanism. The photogrowable nanonetworks (PGNNs) were synthesized by cross-linking two components, a thiolated...
7.
Dau H, Tsogtgerel E, Matyjaszewski K, Harth E
Angew Chem Int Ed Engl
. 2022 May;
61(33):e202205931.
PMID: 35588082
This work develops the Polyolefin Active-Ester Exchange (PACE) process to afford well-defined polyolefin-polyvinyl block copolymers. α-Diimine Pd -catalyzed olefin polymerizations were investigated through in-depth kinetic studies in comparison to an...
8.
Keyes A, Dau H, Matyjaszewski K, Harth E
Angew Chem Int Ed Engl
. 2021 Dec;
61(10):e202112742.
PMID: 34967088
Practical synthesis of polyolefin-polyvinyl block copolymers remains a challenge for transition-metal catalyzed polymerizations. Common approaches functionalize polyolefins for post-radical polymerization via insertion methods, yet sacrifice the livingness of the olefin...
9.
Liu Y, Harth E
Angew Chem Int Ed Engl
. 2021 Aug;
60(45):24107-24115.
PMID: 34403566
The introduction of m-xylyl substituents to α-diimine Pd catalyst promotes living ethylene polymerization at room temperature and low pressure to yield high molecular weight polyethylene (PE) with low branching (<17/1000 ...
10.
Spears B, Marin M, Chaker A, Lampley M, Harth E
ACS Biomater Sci Eng
. 2021 Jan;
2(8):1265-1272.
PMID: 33434980
Microsized particles are versatile drug delivery systems with applications as inhalants, implants, and vaccines. An ideal fabrication technique is envisioned to provide particles with controlled size dimensions and is facile,...