David M Whalley
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Explore the profile of David M Whalley including associated specialties, affiliations and a list of published articles.
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7
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32
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Recent Articles
1.
Whalley D, Carlino L, Putra O, Anderson N, Coote S, Lorthioir O
Chem Sci
. 2024 Nov;
15(46):19564-19570.
PMID: 39568909
The previously unreported combination of nucleophilic phosphine catalysis and energy transfer catalysis allows for the rapid construction of structurally distinct 2-oxabicyclo[2.1.1]hexanes (2-oxa-BCH) from readily available building blocks with high atom...
2.
Kadarauch M, Whalley D, Phipps R
J Am Chem Soc
. 2023 Nov;
145(47):25553-25558.
PMID: 37972383
Arylative phenol dearomatization affords complex, cyclohexanone-based scaffolds from simple starting materials, and asymmetric versions allow access to valuable enantioenriched structures. However, bespoke chiral ligands must typically be identified for each...
3.
Pearce-Higgins R, Hogenhout L, Docherty P, Whalley D, Chuentragool P, Lee N, et al.
J Am Chem Soc
. 2022 Aug;
144(33):15026-15032.
PMID: 35969692
Axial chirality features prominently in molecules of biological interest as well as chiral catalyst designs, and atropisomeric 2,2'-biphenols are particularly prevalent. Atroposelective metal-catalyzed cross-coupling is an attractive and modular approach...
4.
Whalley D, Seayad J, Greaney M
Angew Chem Int Ed Engl
. 2021 Aug;
60(41):22219-22223.
PMID: 34370898
The ring-opening of 3-aminocyclobutanone oximes enables easy generation of primary alkyl radicals, capable of undergoing an unprecedented strain-release, desulfonylative radical Truce-Smiles rearrangement, providing divergent access to valuable 1,3 diamines and...
5.
6.
Whalley D, Duong H, Greaney M
Chem Commun (Camb)
. 2020 Aug;
56(77):11493-11496.
PMID: 32857086
A decarboxylative, desulfonylative Smiles rearrangement is presented that employs activated-ester/energy transfer catalysis to decarboxylate β-amino acid derived starting materials at room-temperature under visible light irradiation. The radical Smiles rearrangement gives...
7.
Whalley D, Duong H, Greaney M
Chemistry
. 2018 Dec;
25(8):1927-1930.
PMID: 30536854
A light-mediated Truce-Smiles arylative rearrangement is described that proceeds in the absence of any photocatalyst. The protocol creates two C-C bonds from simple starting materials, with the installation of an...