Clement Falaise
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Explore the profile of Clement Falaise including associated specialties, affiliations and a list of published articles.
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46
Citations
163
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Recent Articles
1.
Marrot J, Falaise C, Abou Fadel M, Leclerc N, Haouas M, Floquet S, et al.
Inorg Chem
. 2025 Feb;
64(8):4017-4024.
PMID: 39961100
Polycondensation processes of metalate ions in the presence of a dinuclear linker {MoES} (E = O, S) and weakly chelating ligands such as acetate or sulfate lead to giant polyoxometalate...
2.
Segado-Centellas M, Falaise C, Leclerc N, Mpacko Priso G, Haouas M, Cadot E, et al.
Chem Sci
. 2024 Sep;
PMID: 39282647
Chaotropic polyoxometalates (POMs) form robust host-guest complexes with γ-cyclodextrin (γ-CD), offering promising applications in catalysis, electrochemical energy storage, and nanotechnology. In this article, we provide the first computational insights on...
3.
Lion M, Marrot J, Shepard W, Leclerc N, Haouas M, Cadot E, et al.
Chempluschem
. 2024 Sep;
90(1):e202400475.
PMID: 39248048
Desolvation processes, though common in self-assembled biological structures, are rarely evidenced and utilized in the design of crystalline architectures. In this study, we introduce a novel approach using the [MoSO(OH)(guest)]...
4.
Falaise C, Khlifi S, Bauduin P, Schmid P, Degrouard J, Leforestier A, et al.
J Am Chem Soc
. 2024 Jan;
146(2):1501-1511.
PMID: 38189235
The self-assembly of organic amphiphilic species into various aggregates such as spherical or elongated micelles and cylinders up to the formation of lyotropic hexagonal or lamellar phases results from cooperative...
5.
Khlifi S, Yao S, Falaise C, Bauduin P, Guerineau V, Leclerc N, et al.
Chemistry
. 2023 Dec;
30(18):e202303815.
PMID: 38146753
Supramolecular polymers built from stimuli-responsive host-guest interactions represent an attractive way of tailoring smart materials. Herein, we exploit the chaotropic effect of polyoxometalates and related host-guest properties to design unconventional...
6.
Mpacko Priso G, Haouas M, Leclerc N, Falaise C, Cadot E
Angew Chem Int Ed Engl
. 2023 Oct;
62(49):e202312457.
PMID: 37831589
Super-reduction of polyoxometalates (POMs) in solution is of fundamental interest for designing innovative energy storage systems. In this article, we show that the "Dawson-like" POM can undergo a disproportionation process...
7.
Haouas M, Falaise C, Leclerc N, Floquet S, Cadot E
Dalton Trans
. 2023 Sep;
52(38):13467-13481.
PMID: 37691564
Natural cyclodextrin (CD) macrocycles are known to form diverse inclusion complexes with a wide variety of organic molecules, but recent work has revealed that inorganic clusters also form multicomponent supramolecular...
8.
Fatima A, Smortsova Y, Falaise C, Leclerc N, Haouas M, Cadot E, et al.
Chem Commun (Camb)
. 2023 Aug;
59(73):10988-10991.
PMID: 37615655
Evidence for photoinduced intermolecular electron transfer from the excited state of the [MoICl] electron-rich cluster to polyoxometalates (POMs) is reported. We demonstrate that the global charge density of POMs affects...
9.
Cebotari D, Calancea S, Marrot J, Guillot R, Falaise C, Guerineau V, et al.
Dalton Trans
. 2023 Feb;
52(10):3059-3071.
PMID: 36779751
[MoV2OS]-based thiosemicarbazone complexes appear as very promising molecules for biological applications due to the intrinsic properties of their components. This paper deals with the synthesis and characterization of six coordination...
10.
Falaise C, Mpacko Priso G, Leclerc N, Haouas M, Cadot E
Inorg Chem
. 2023 Jan;
62(6):2494-2502.
PMID: 36716738
Polyoxometalates (POMs) represent a promising class of molecular electron reservoirs. However, their multielectron reduction gives rise to intricate physical-chemical phenomena that must be fully understood for their future use in...