Bernd von Issendorff
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Explore the profile of Bernd von Issendorff including associated specialties, affiliations and a list of published articles.
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47
Citations
171
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Recent Articles
1.
Richter F, Saalmann U, Allaria E, Wollenhaupt M, Ardini B, Brynes A, et al.
Nature
. 2024 Dec;
636(8042):337-341.
PMID: 39663491
Tailored light-matter interactions in the strong coupling regime enable the manipulation and control of quantum systems with up to unit efficiency, with applications ranging from quantum information to photochemistry. Although...
2.
Abrupt Change from Ionic to Covalent Bonding in Nickel Halides Accompanied by Ligand Field Inversion
Flach M, Hirsch K, Gitzinger T, Timm M, da Silva Santos M, Ablyasova O, et al.
Inorg Chem
. 2024 Jun;
63(25):11812-11820.
PMID: 38857413
The electronic configuration of transition metal centers and their ligands is crucial for redox reactions in metal catalysis and electrochemistry. We characterize the electronic structure of gas-phase nickel monohalide cations...
3.
Haitjema J, Castellanos S, Lugier O, Bespalov I, Lindblad R, Timm M, et al.
Phys Chem Chem Phys
. 2024 Jan;
26(7):5986-5998.
PMID: 38293812
"Tin-oxo cage" organometallic compounds are considered as photoresists for extreme ultraviolet (EUV) photolithography. To gain insight into their electronic structure and reactivity to ionizing radiation, we trapped bare gas-phase -butyltin-oxo...
4.
da Silva Santos M, Medel R, Flach M, Ablyasova O, Timm M, von Issendorff B, et al.
Chemphyschem
. 2023 Aug;
24(22):e202300390.
PMID: 37589334
The tetraoxido ruthenium(VIII) radical cation, [RuO ] , should be a strong oxidizing agent, but has been difficult to produce and investigate so far. In our X-ray absorption spectroscopy study,...
5.
Colombo A, Dold S, Kolb P, Bernhardt N, Behrens P, Correa J, et al.
Sci Adv
. 2023 Feb;
9(8):eade5839.
PMID: 36812315
The structure and dynamics of isolated nanosamples in free flight can be directly visualized via single-shot coherent diffractive imaging using the intense and short pulses of x-ray free-electron lasers. Wide-angle...
6.
Flach M, Hirsch K, Timm M, Ablyasova O, da Silva Santos M, Kubin M, et al.
Phys Chem Chem Phys
. 2022 Aug;
24(33):19890-19894.
PMID: 35959850
Oxidation states are integer in number but d configurations of transition metal centers vary continuously in polar bonds. We quantify the shifts of the iron L excitation energy, within the...
7.
Wang K, Yin G, Jia Z, Miao L, Moro R, von Issendorff B, et al.
Phys Chem Chem Phys
. 2022 Jul;
24(30):18321-18330.
PMID: 35880636
We investigated the structural evolution and electronic properties of medium-sized silicon cluster anions doped with two transition metal atoms, TMSi (TM = V, Cr; = 14-20), by using mass-selective anion...
8.
da Silva Santos M, Stuker T, Flach M, Ablyasova O, Timm M, von Issendorff B, et al.
Angew Chem Int Ed Engl
. 2022 Jul;
61(38):e202207688.
PMID: 35818987
Although the highest possible oxidation states of all transition elements are rare, they are not only of fundamental interest but also relevant as potentially strong oxidizing agents. In general, the...
9.
Wang K, Jia Z, Fan Z, Zhao H, Yin G, Moro R, et al.
Phys Chem Chem Phys
. 2022 Mar;
24(15):8839-8845.
PMID: 35355038
We present a systematic study of the structures and electronic properties of vanadium-doped silicon cluster anions, VSi ( = 14-20), by combining photoelectron spectroscopy (PES) measurements and density functional theory...
10.
Wang X, Rathnachalam S, Zamudio-Bayer V, Bijlsma K, Li W, Hoekstra R, et al.
Phys Chem Chem Phys
. 2022 Mar;
24(13):7815-7825.
PMID: 35297440
We present experimental evidence for soft X-ray induced intramolecular hydrogen transfer in the protonated synthetic tri-oligonucleotide (UAG) in the gas-phase (U: fluorouracil). The trinucleotide cations were stored in a cryogenic...