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Antoine Simonneau

Explore the profile of Antoine Simonneau including associated specialties, affiliations and a list of published articles. Areas
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Articles 26
Citations 158
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Recent Articles
1.
Bonfante S, Tanner T, Lorber C, Lynam J, Simonneau A, Slattery J
Chem Sci . 2025 Jan; 16(8):3552-3559. PMID: 39867955
Polarity reversal, or "umpolung", is a widely acknowledged strategy to allow organic functional groups amenable to react in alternative ways to the usual preference set by their electronic features. In...
2.
Estival A, Blancarte L, Pinto L, Pointis R, Galas N, Sournia-Saquet A, et al.
Dalton Trans . 2025 Jan; 54(7):2860-2870. PMID: 39792086
Functional pincer ligands that engage in metal-ligand cooperativity and/or are capable of redox non-innocence have found a great deal of success in catalysis. These two properties may be found in...
3.
Queyriaux N, Cabrera-Trujillo J, Durvin N, Vendier L, Miqueu K, Simonneau A
Chem Sci . 2024 Nov; 15(48):20582-20589. PMID: 39600508
The cationic molybdenum pentahydride complex [MoH(depe)] (depe = 1,2-bis(diethylphosphino)ethane) is shown to undergo two consecutive reactions with carbon dioxide. In the initial, room-temperature process, classical insertion of CO into a...
4.
Escomel L, Le De Q, Benonie M, Vendier L, Simonneau A
Chem Commun (Camb) . 2024 Oct; 60(90):13235-13238. PMID: 39445414
Donor-acceptor systems for CO activation combining a formally zero-valent group 6 metal as the donor with the Lewis acid Al(CF) (AlCF) are reported. They were obtained from AlCF adducts of...
5.
Escomel L, Martins F, Vendier L, Coffinet A, Queyriaux N, Krewald V, et al.
Chem Sci . 2024 Jul; 15(29):11321-11336. PMID: 39055009
The coordination of the Lewis superacid tris(pentafluorophenyl)alane (AlCF) to phosphine-supported, group 6 bis(dinitrogen) complexes [ML(N)] is explored, with M = Cr, Mo or W and L = dppe (1,2-bis(diphenylphosphino)ethane), depe...
6.
Boegli M, Coffinet A, Bijani C, Simonneau A
Chem Asian J . 2024 Jun; 19(17):e202400451. PMID: 38864406
The adducts 2 of general formula trans-[(L)M{RP(CH)PR}{NB(CF)}] (L=ø or N, M=Mo or W, R=Et or Ph), formed from Lewis acid-base pairing of B(CF) to a dinitrogen ligand of zero-valent group...
7.
Le De Q, Valyaev D, Simonneau A
Chemistry . 2024 May; 30(39):e202400784. PMID: 38709147
Manganese is currently experiencing a great deal of attention in homogeneous catalysis as a sustainable alternative to platinum group metals due to its abundance, affordable price and low toxicity. While...
8.
Bonfante S, Lorber C, Lynam J, Simonneau A, Slattery J
J Am Chem Soc . 2024 Apr; PMID: 38606948
No abstract available.
9.
Bonfante S, Lorber C, Lynam J, Simonneau A, Slattery J
J Am Chem Soc . 2024 Jan; 146(3):2005-2014. PMID: 38207215
Delivering metallomimetic reactivity from simple p-block compounds is highly desirable in the search to replace expensive, scarce precious metals by cheap and abundant elements in catalysis. This contribution demonstrates that...
10.
Specklin D, Boegli M, Coffinet A, Escomel L, Vendier L, Grellier M, et al.
Chem Sci . 2023 Dec; 14(48):14262-14270. PMID: 38098710
A Lewis superacidic bis(borane) CF{B(CF)} was reacted with tungsten N-complexes [W(N)(RPCHCHPR)] (R = Ph or Et), affording zwitterionic boryldiazenido W(ii) complexes -[W(L)(RPCHCHPR)(N{B(CF)(CFB(CF)})] (L = ø, N or THF). These compounds...