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Andrey E Boguslavskiy

Explore the profile of Andrey E Boguslavskiy including associated specialties, affiliations and a list of published articles. Areas
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Articles 34
Citations 99
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Recent Articles
1.
Morrigan L, Neville S, Gregory M, Boguslavskiy A, Forbes R, Wilkinson I, et al.
Phys Rev Lett . 2023 Nov; 131(19):193001. PMID: 38000424
We develop and experimentally demonstrate a methodology for a full molecular frame quantum tomography (MFQT) of dynamical polyatomic systems. We exemplify this approach through the complete characterization of an electronically...
2.
Goudreau E, Boguslavskiy A, Moffatt D, Makhija V, Hemsworth M, Lausten R, et al.
Rev Sci Instrum . 2023 Oct; 94(6). PMID: 37862509
The 2D photoelectron velocity map imaging (VMI) technique is commonly employed in gas-phase molecular spectroscopy and dynamics investigations due to its ability to efficiently extract photoelectron spectra and angular distributions...
3.
Forbes R, Neville S, Larsen M, Roder A, Boguslavskiy A, Lausten R, et al.
J Phys Chem Lett . 2021 Aug; 12(35):8541-8547. PMID: 34464141
We combined tunable vacuum-ultraviolet time-resolved photoelectron spectroscopy (VUV-TRPES) with high-level quantum dynamics simulations to disentangle multistate Rydberg-valence dynamics in acetone. A femtosecond 8.09 eV pump pulse was tuned to the...
4.
Williams M, Forbes R, Weir H, Veyrinas K, MacDonell R, Boguslavskiy A, et al.
J Phys Chem Lett . 2021 Jul; 12(27):6363-6369. PMID: 34231356
We present the first vacuum ultraviolet time-resolved photoelectron spectroscopy (VUV-TRPES) study of photoisomerization dynamics in the paradigmatic molecule -stilbene. A key reaction intermediate in its dynamics, known as the phantom...
5.
Makhija V, Boguslavskiy A, Forbes R, Veyrinas K, Wilkinson I, Lausten R, et al.
Faraday Discuss . 2021 Feb; 228(0):191-225. PMID: 33629690
The optical formation of coherent superposition states, a wavepacket, can allow the study of zeroth-order states, the evolution of which exhibit structural and electronic changes as a function of time:...
6.
Herperger K, Roder A, MacDonell R, Boguslavskiy A, Skov A, Stolow A, et al.
J Chem Phys . 2020 Dec; 153(24):244307. PMID: 33380089
Functional group substituents are a ubiquitous tool in ground-state organic chemistry often employed to fine-tune chemical properties and obtain desired chemical reaction outcomes. Their effect on photoexcited electronic states, however,...
7.
Roder A, Skov A, Boguslavskiy A, Lausten R, Stolow A
Phys Chem Chem Phys . 2020 Nov; 22(45):26241-26254. PMID: 33174560
The vacuum ultraviolet (VUV) absorption spectra of cyclic ethers consist primarily of Rydberg ← n transitions. By studying three cyclic ethers of varying ring size (tetrahydropyran, tetrahydrofuran and trimethylene oxide,...
8.
MacDonell R, Corrales M, Boguslavskiy A, Banares L, Stolow A, Schuurman M
J Chem Phys . 2020 Mar; 152(8):084308. PMID: 32113357
The photochemical dynamics of double-bond-containing hydrocarbons is exemplified by the smallest alkenes, ethylene and butadiene. Chemical substituents can alter both decay timescales and photoproducts through a combination of inertial effects...
9.
Larsen M, Solling T, Forbes R, Boguslavskiy A, Makhija V, Veyrinas K, et al.
J Chem Phys . 2019 Feb; 150(5):054301. PMID: 30736696
Time-resolved photoelectron spectroscopy in combination with ab initio quantum chemistry calculations was used to study ultrafast excited state dynamics in formamide (FOR), N,N-dimethylformamide (DMF), and N,N-dimethylacetamide (DMA) following 160 nm...
10.
Coates M, Larsen M, Forbes R, Neville S, Boguslavskiy A, Wilkinson I, et al.
J Chem Phys . 2018 Oct; 149(14):144311. PMID: 30316260
The vacuum-ultraviolet photoinduced dynamics of cyclopropane (CH) were studied using time-resolved photoelectron spectroscopy (TRPES) in conjunction with quantum dynamics simulations. Following excitation at 160.8 nm, and subsequent probing via photoionization...