Alberto Martinez-Cuezva
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Explore the profile of Alberto Martinez-Cuezva including associated specialties, affiliations and a list of published articles.
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31
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182
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Recent Articles
1.
Pastor A, Lopez-Leonardo C, Cutillas-Font G, Martinez-Cuezva A, Marin-Luna M, Garcia-Lopez J, et al.
Org Lett
. 2024 Dec;
27(1):73-79.
PMID: 39707992
Intramolecular reactions between isocyano and iminophosphorane functions yield species containing an embedded 1,3,2-diazaphosphetidine ring, as result of the [2 + 2] cycloaddition of the primary reactive product, the cyclic carbodiimide,...
2.
Orlando T, Weimer G, Salbego P, Martinez-Cuezva A, Berna J, Martins M
Chemistry
. 2024 Sep;
30(64):e202403276.
PMID: 39312443
One of the most recent focuses in supramolecular chemistry is developing molecules designed to exhibit programmable properties at the molecular level. Rotaxanes, which function as molecular machines with movements controlled...
3.
Cutillas-Font G, Pastor A, Alajarin M, Martinez-Cuezva A, Marin-Luna M, Batanero B, et al.
Chem Sci
. 2024 Aug;
15(34):13823-13831.
PMID: 39211492
Aza-Pechmann derivatives have emerged as interesting building blocks for the preparation of organic electronic devices. The development of methodologies aimed to enhance their chemical stability and modulate their physical and...
4.
Razi S, Marin-Luna M, Alajarin M, Martinez-Cuezva A, Berna J
Commun Chem
. 2024 Aug;
7(1):170.
PMID: 39098851
The development of efficient methods for the synthesis of mechanically interlocked compounds is currently considered a major challenge in supramolecular chemistry. Twofold vinylogous fumaramides, a class of conjugated bis(enaminones), successfully...
5.
Puigcerver J, Zamora-Gallego J, Marin-Luna M, Martinez-Cuezva A, Berna J
J Am Chem Soc
. 2024 Jul;
146(33):22887-22892.
PMID: 38975636
We finely designed a set of [2]rotaxanes with urea threads and tested them as hydrogen-bonding phase-transfer catalysts in two different nucleophilic substitutions requiring the activation of the reactant fluoride anion....
6.
Saura-Sanmartin A, Cutillas-Font G, Martinez-Cuezva A, Alajarin M, Esteban-Betegon F, Pena-Sanchez P, et al.
Chem Commun (Camb)
. 2024 Jun;
60(50):6431-6434.
PMID: 38829284
The preparation of highly rigid cobalt(II)- and copper(II)-organic frameworks incorporating a tetralactam [2]rotaxane as a ligand is described. The interlocked ligand is functionalized with two pairs of carboxylate groups placed...
7.
Puigcerver J, Marin-Luna M, Iglesias-Siguenza J, Alajarin M, Martinez-Cuezva A, Berna J
J Am Chem Soc
. 2024 Jan;
146(5):2882-2887.
PMID: 38266249
Herein we describe an effective transmission of chirality, from mechanically planar chirality to point chirality, in hydrogen-bonded [2]rotaxanes. A highly selective mono-N-methylation of one (out of four) amide N atom...
8.
Puigcerver J, Alajarin M, Martinez-Cuezva A, Berna J
Org Biomol Chem
. 2023 Nov;
21(45):9070-9075.
PMID: 37938860
In this study, we show the effect of the -dimethyl substitution at the four benzylic carbons of the ring on the internal dynamics of two-station [2]rotaxanes. Such structural modification of...
9.
Saura-Sanmartin A, Nicolas-Garcia T, Pastor A, Quinonero D, Alajarin M, Martinez-Cuezva A, et al.
Chem Sci
. 2023 Apr;
14(15):4143-4151.
PMID: 37063802
The synthesis of a ditopic interlocked building-block and its self-assembly into a cyclic dimer is reported herein. Starting from a thread with two recognition sites, a three-component clipping reaction was...
10.
de Maria Perez J, Alajarin M, Martinez-Cuezva A, Berna J
Angew Chem Int Ed Engl
. 2023 Mar;
62(21):e202302681.
PMID: 36952651
Glutaconamide-based [2]rotaxanes are efficiently oxidized to the respective interlocked α-ketoamides, whereas their non-interlocked threads afford hydroxycyclohexene tetraamides under similar reaction conditions. These results showcase the mechanically interlocking of highly reactive...