Akshay M Nair
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Explore the profile of Akshay M Nair including associated specialties, affiliations and a list of published articles.
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17
Citations
31
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Recent Articles
1.
Nair A, Martinez-Balart P, Barbeira-Aran S, Fananas-Mastral M
Angew Chem Int Ed Engl
. 2024 Sep;
64(2):e202416957.
PMID: 39316730
Gaseous alkanes represent the most abundant carbon-based chemical feedstocks in our planet. However, the intrinsic inertness of their C-H bonds has rendered the use of these alkanes very difficult for...
2.
Nair A, Rahaman R, Patra J, Volla C
Org Lett
. 2024 Sep;
26(37):7822-7827.
PMID: 39255343
In the realm of organic synthesis, direct C-H alkynylation with arylacetylenes has remained a daunting challenge due to competing annulations or alkenylation. Addressing this long-standing issue, herein we demonstrate the...
3.
Patra J, Nair A, Volla C
Chem Sci
. 2024 May;
15(19):7136-7143.
PMID: 38756813
Bismuth, in spite of its low cost and low toxicity, has found limited application in organic synthesis. Although the photoactivity of Bi(iii) salts has been well studied, this has not...
4.
Khan S, Chatterjee A, Nair A, Volla C
Org Biomol Chem
. 2024 Apr;
22(19):3887-3892.
PMID: 38683654
We hereby report a highly diastereoselective synthesis of chalcogenated azaspirotricycles a one-pot Ugi/spirocyclization/aza-Michael addition sequence. The reaction proceeds a key visible light mediated spirocyclization step under mild, metal-free and energy...
5.
Halder I, Nair A, Volla C
Chem Commun (Camb)
. 2023 Apr;
59(39):5862-5865.
PMID: 37092312
We hereby report a visible light mediated alkyl sulfonylative cascade cyclization of alkynyl and dialkynyl cyclohexadienones SO insertion. The protocol utilizes alkyl Hantzsch esters as the alkyl source and DABSO...
6.
Kumar S, Nair A, Patra J, Volla C
Org Lett
. 2023 Feb;
25(7):1114-1119.
PMID: 36791284
Naphthoquinones form the core of a variety of drugs and natural products. As a result, the conjugation of 1,4-naphthoquinones with organic building blocks would offer a facile strategy toward scaffolds...
7.
Shukla R, Nair A, Volla C
Chem Sci
. 2023 Feb;
14(4):955-962.
PMID: 36755729
Recent years have seen the emergence of transition metal catalyzed C-H activation as a powerful synthetic tool in organic chemistry. Allenes have fascinated synthetic chemists due to their unique reactivity....
8.
Halder I, Nair A, Giri S, Volla C
Org Lett
. 2023 Feb;
25(5):826-831.
PMID: 36722745
Herein, we report a reductive hydrazo-sulfonylative difunctionalization cascade of alkynyl cyclohexadienones employing PhTeTePh as an uncommon reducing agent. Diphenyl ditelluride is a commercially available solid with a good solubility profile...
9.
Kumar S, Nair A, Volla C
Chem Asian J
. 2022 Aug;
17(19):e202200801.
PMID: 35939065
Herein, we developed two distinct pyridine N-oxide directed C-H activation protocols to achieve [4+1] annulation and alkoxylation of benzamide derivatives by merging Co-catalysis with visible-light photoredox catalysis. The protocols deliver...
10.
Rahaman R, Nair A, Volla C
Chemistry
. 2022 Jun;
28(50):e202201290.
PMID: 35670550
We hereby disclose, a visible light mediated addition of sulfenyl radicals to trialkyl phosphites to access functionalized phosphorothioates. The use of cheap and readily available Eosin Y as a photocatalyst...