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Adam F Sapnik

Explore the profile of Adam F Sapnik including associated specialties, affiliations and a list of published articles. Areas
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Articles 22
Citations 132
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Recent Articles
1.
Esser G, Crits R, de Meester J, Robeyns K, Leyssens T, Chernyshov D, et al.
Inorg Chem . 2025 Feb; 64(9):4491-4500. PMID: 40007100
Metal-organic frameworks (MOFs) are an interesting class of inorganic/organic hybrid materials with a wide scope of applications. Although manganese is an abundant metal, the synthesis of Mn(III)-containing MOFs has not...
2.
Shaw B, Corti L, Tuffnell J, Castillo-Blas C, Schlachta P, Robertson G, et al.
Inorg Chem . 2024 Dec; 63(52):24812-24824. PMID: 39696790
ABX-type hybrid organic-inorganic structures have recently emerged as a new class of meltable materials. Here, by the use of phenylphosphonium derivatives as A cation, we study liquid- and glass-forming behavior...
3.
Chester A, Castillo-Blas C, Sajzew R, Rodrigues B, Lampronti G, Sapnik A, et al.
Dalton Trans . 2024 Jun; 53(25):10655-10665. PMID: 38860528
Here we describe the synthesis of a compositional series of metal-organic framework crystalline-inorganic glass composites (MOF-CIGCs) containing ZIF-8 and an inorganic phosphate glass, 20NaO-10NaCl-70PO, to expand the library of host...
4.
Sapnik A, Thorne M, Castillo-Blas C, Keenan L, Johnson T, Bennett T
Soft Matter . 2024 Feb; 20(10):2338-2347. PMID: 38372182
Amorphous metal-organic frameworks are rarely formed direct synthesis. Our limited understanding of their atomic assembly in solution prevents full exploitation of their unique structural complexity. Here, we use synchrotron X-ray...
5.
Chester A, Castillo-Blas C, Sajzew R, Rodrigues B, Mas-Balleste R, Moya A, et al.
Chem Sci . 2023 Nov; 14(42):11737-11748. PMID: 37920351
Recently, increased attention has been focused on amorphous metal-organic frameworks (MOFs) and, more specifically, MOF glasses, the first new glass category discovered since the 1970s. In this work, we explore...
6.
Castillo-Blas C, Chester A, Cosquer R, Sapnik A, Corti L, Sajzew R, et al.
J Am Chem Soc . 2023 Oct; 145(42):22913-22924. PMID: 37819708
The interface within a composite is critically important for the chemical and physical properties of these materials. However, experimental structural studies of the interfacial regions within metal-organic framework (MOF) composites...
7.
Sapnik A, Sun C, Laulainen J, Johnstone D, Brydson R, Johnson T, et al.
Commun Chem . 2023 May; 6(1):92. PMID: 37169838
Intentionally disordered metal-organic frameworks (MOFs) display rich functional behaviour. However, the characterisation of their atomic structures remains incredibly challenging. X-ray pair distribution function techniques have been pivotal in determining their...
8.
Bumstead A, Castillo-Blas C, Pakamore I, Thorne M, Sapnik A, Chester A, et al.
Chem Commun (Camb) . 2022 Dec; 59(6):732-735. PMID: 36541403
The chemistries that can be incorporated within melt-quenched zeolitic imidazolate framework (ZIF) glasses are currently limited. Here we describe the preparation of a previously unknown purine-containing ZIF which we name...
9.
Bechis I, Sapnik A, Tarzia A, Wolpert E, Addicoat M, Keen D, et al.
Chem Mater . 2022 Oct; 34(20):9042-9054. PMID: 36313398
Amorphous metal-organic frameworks (MOFs) are a class of disordered framework materials with a defined local order given by the connectivity between inorganic nodes and organic linkers, but absent long-range order....
10.
Thorne M, Castillo-Blas C, McHugh L, Bumstead A, Robertson G, Sapnik A, et al.
Chem Commun (Camb) . 2022 Oct; 58(85):11949-11952. PMID: 36205108
The structure of a new ZIF-8 polymorph with quartz topology (qtz) is reported. This qtz-[Zn(mIm)2] phase was obtained by mechanically amorphising crystalline ZIF-8, before heating the resultant amorphous phase to...