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Structure-spectrum Correlations in Nucleic Acids. I. Raman Lines in the 600-700 Cm-1 Range of Guanosine Residue

Overview
Journal Nucleic Acids Res
Publisher Oxford University Press
Specialty Biochemistry
Date 1984 Sep 11
PMID 6091044
Citations 5
Authors
Y Nishimura
M Tsuboi
T Sato
Affiliations
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Abstract

Raman spectra of nine crystals of known structures which involve guanosine moieties with various conformations have been observed. It has been established that a guanosine residue with the C3'endo-anti conformation gives a strong Raman line at 666 +/- 2 cm-1. It has also been found that the residue with 04'endo-anti gives a strong Raman line at 682 cm-1, and C3'exo-syn at 616 cm-1. The usefulness of these structure-spectrum correlations in the conformation studies of polynucleotides are shown.

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