Synthesis, Structure and Iodine Adsorption Properties of a Ni Cluster-Based Supramolecular Framework

Overview

Journal Molecules

Publisher MDPI

Specialty Biology

Date 2025 Mar 13

PMID 40076214

Authors

Jingyi Qiu

Linxia Tang

Ziang Nan

Luyao Liu

Qing Li

Wei Wang

Zhu Zhuo

Dongwei Zhang

Yougui Huang

Liangliang Zhang

Affiliations

Soon will be listed here.

Abstract

The capture of radioactive iodine (129I or 131I) is of significant importance for the production of nuclear power and the treatment of nuclear waste. In recent years, crystallized porous materials have been extensively investigated to achieve highly effective adsorption of radioactive iodine. Herein, by using the hydrothermal method, a Ni cluster-based framework () was successfully constructed through a self-assembly process. Driven by the stacking interactions between -electron-rich benzimidazole groups, [NiS] clusters stack in a lattice, forming a porous framework with proper channels, rendering compound as an ideal adsorbent for iodine. Compound delivered a capability of iodine adsorption (2.08 g g- and 560 mg g- for gaseous and solution iodine, respectively) with stable cyclability.

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